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2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol

In the title compound, C(16)H(14)ClN(3)O(3)S, the thia­zine ring adopts a sofa (half-chair) conformation, with an r.m.s. deviation from the mean plane of 0.23 Å. The S atom and S-bonded C atom exhibit the maximum deviations from the thia­zine mean plane [−0.3976 (12) and 0.3179 (14) Å, respectively]...

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Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Zia-ur-Rehman, Muhammad, Arshad, Muhammad Nadeem, Asiri, Abdullah M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275000/
https://www.ncbi.nlm.nih.gov/pubmed/22346945
http://dx.doi.org/10.1107/S1600536811055978
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author Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
author_sort Shafiq, Muhammad
collection PubMed
description In the title compound, C(16)H(14)ClN(3)O(3)S, the thia­zine ring adopts a sofa (half-chair) conformation, with an r.m.s. deviation from the mean plane of 0.23 Å. The S atom and S-bonded C atom exhibit the maximum deviations from the thia­zine mean plane [−0.3976 (12) and 0.3179 (14) Å, respectively]. The conformations around the double bonds in the R (2)C=N—N=CHR unit are Z and E. An intra­molecular O—H⋯N hydrogen bond with the hy­droxy group as donor generates an S(6) ring motif. In the crystal, pairs of weak C—H⋯O inter­actions connect the mol­ecules, forming inversion dimers.
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spelling pubmed-32750002012-02-15 2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol Shafiq, Muhammad Khan, Islam Ullah Zia-ur-Rehman, Muhammad Arshad, Muhammad Nadeem Asiri, Abdullah M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(14)ClN(3)O(3)S, the thia­zine ring adopts a sofa (half-chair) conformation, with an r.m.s. deviation from the mean plane of 0.23 Å. The S atom and S-bonded C atom exhibit the maximum deviations from the thia­zine mean plane [−0.3976 (12) and 0.3179 (14) Å, respectively]. The conformations around the double bonds in the R (2)C=N—N=CHR unit are Z and E. An intra­molecular O—H⋯N hydrogen bond with the hy­droxy group as donor generates an S(6) ring motif. In the crystal, pairs of weak C—H⋯O inter­actions connect the mol­ecules, forming inversion dimers. International Union of Crystallography 2012-01-07 /pmc/articles/PMC3275000/ /pubmed/22346945 http://dx.doi.org/10.1107/S1600536811055978 Text en © Shafiq et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Zia-ur-Rehman, Muhammad
Arshad, Muhammad Nadeem
Asiri, Abdullah M.
2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
title 2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
title_full 2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
title_fullStr 2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
title_full_unstemmed 2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
title_short 2-{(E)-[(2Z)-(3-Chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1H-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
title_sort 2-{(e)-[(2z)-(3-chloro-1-methyl-2,2-di­oxo-3,4-dihydro-1h-2,1-benzo­thia­zin-4-yl­idene)hydrazinyl­idene]meth­yl}phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275000/
https://www.ncbi.nlm.nih.gov/pubmed/22346945
http://dx.doi.org/10.1107/S1600536811055978
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