N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide

In the title compound, C(12)H(9)FN(2)OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 87.08 (16)°] oriented towards the ortho-H atom of the benzene ring. The mol­ecule is nearly planar, the dihedral angle between the thio­phene and benzene ri...

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Autores principales: Alanazi, Amer M., Lahsasni, Siham, El-Emam, Ali A., Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275004/
https://www.ncbi.nlm.nih.gov/pubmed/22346949
http://dx.doi.org/10.1107/S1600536811056121
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author Alanazi, Amer M.
Lahsasni, Siham
El-Emam, Ali A.
Ng, Seik Weng
author_facet Alanazi, Amer M.
Lahsasni, Siham
El-Emam, Ali A.
Ng, Seik Weng
author_sort Alanazi, Amer M.
collection PubMed
description In the title compound, C(12)H(9)FN(2)OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 87.08 (16)°] oriented towards the ortho-H atom of the benzene ring. The mol­ecule is nearly planar, the dihedral angle between the thio­phene and benzene rings being 13.0 (2)° in the major component. The azomethine C=N double bond in the mol­ecule is of an E configuration. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers.
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spelling pubmed-32750042012-02-15 N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide Alanazi, Amer M. Lahsasni, Siham El-Emam, Ali A. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(9)FN(2)OS, the thienyl ring is disordered over two positions, with the S atom of the major component [occupancy = 87.08 (16)°] oriented towards the ortho-H atom of the benzene ring. The mol­ecule is nearly planar, the dihedral angle between the thio­phene and benzene rings being 13.0 (2)° in the major component. The azomethine C=N double bond in the mol­ecule is of an E configuration. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275004/ /pubmed/22346949 http://dx.doi.org/10.1107/S1600536811056121 Text en © Alanazi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Alanazi, Amer M.
Lahsasni, Siham
El-Emam, Ali A.
Ng, Seik Weng
N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
title N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
title_full N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
title_fullStr N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
title_full_unstemmed N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
title_short N′-[(1E)-(4-Fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
title_sort n′-[(1e)-(4-fluoro­phen­yl)methyl­idene]thio­phene-2-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275004/
https://www.ncbi.nlm.nih.gov/pubmed/22346949
http://dx.doi.org/10.1107/S1600536811056121
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