2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate

In the title mol­ecule, C(19)H(18)Br(4)N(2)O(2), the dihedral angle between the benzene rings is 73.9 (2)°. Two intra­molecular N—H⋯O hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules are linked via C—H⋯O inter­actions, forming chains propagating along the a-axis directon. A short C⋯B...

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Autores principales: Kargar, Hadi, Kia, Reza, Haghshenas, Mahbubeh, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275012/
https://www.ncbi.nlm.nih.gov/pubmed/22346957
http://dx.doi.org/10.1107/S1600536811055899
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author Kargar, Hadi
Kia, Reza
Haghshenas, Mahbubeh
Tahir, Muhammad Nawaz
author_facet Kargar, Hadi
Kia, Reza
Haghshenas, Mahbubeh
Tahir, Muhammad Nawaz
author_sort Kargar, Hadi
collection PubMed
description In the title mol­ecule, C(19)H(18)Br(4)N(2)O(2), the dihedral angle between the benzene rings is 73.9 (2)°. Two intra­molecular N—H⋯O hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules are linked via C—H⋯O inter­actions, forming chains propagating along the a-axis directon. A short C⋯Br [3.401 (5) Å] contact is present in the crystal structure, which is further stabilized by a π–π inter­action [centroid–centroid distance = 3.739 (3) Å].
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spelling pubmed-32750122012-02-15 2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate Kargar, Hadi Kia, Reza Haghshenas, Mahbubeh Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(19)H(18)Br(4)N(2)O(2), the dihedral angle between the benzene rings is 73.9 (2)°. Two intra­molecular N—H⋯O hydrogen bonds make S(6) ring motifs. In the crystal, mol­ecules are linked via C—H⋯O inter­actions, forming chains propagating along the a-axis directon. A short C⋯Br [3.401 (5) Å] contact is present in the crystal structure, which is further stabilized by a π–π inter­action [centroid–centroid distance = 3.739 (3) Å]. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275012/ /pubmed/22346957 http://dx.doi.org/10.1107/S1600536811055899 Text en © Kargar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kargar, Hadi
Kia, Reza
Haghshenas, Mahbubeh
Tahir, Muhammad Nawaz
2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
title 2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
title_full 2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
title_fullStr 2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
title_full_unstemmed 2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
title_short 2,4-Dibromo-6-[(E)-({3-[(E)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
title_sort 2,4-dibromo-6-[(e)-({3-[(e)-(3,5-dibromo-2-oxidobenzyl­idene)aza­nium­yl]-2,2-dimethyl­prop­yl}iminium­yl)meth­yl]phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275012/
https://www.ncbi.nlm.nih.gov/pubmed/22346957
http://dx.doi.org/10.1107/S1600536811055899
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