(E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide

In the title mol­ecule, C(9)H(11)N(3)O(2)S, an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked via pairs of N—H⋯S inter­actions, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are further linked via N—H⋯S and N—H⋯O hydroge...

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Detalles Bibliográficos
Autores principales: Adabi Ardakani, Amir, Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275013/
https://www.ncbi.nlm.nih.gov/pubmed/22346958
http://dx.doi.org/10.1107/S1600536811056182
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author Adabi Ardakani, Amir
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_facet Adabi Ardakani, Amir
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
author_sort Adabi Ardakani, Amir
collection PubMed
description In the title mol­ecule, C(9)H(11)N(3)O(2)S, an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked via pairs of N—H⋯S inter­actions, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are further linked via N—H⋯S and N—H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to (100). The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.7972 (9) Å].
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spelling pubmed-32750132012-02-15 (E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide Adabi Ardakani, Amir Kargar, Hadi Kia, Reza Tahir, Muhammad Nawaz Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(9)H(11)N(3)O(2)S, an intra­molecular O—H⋯N hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked via pairs of N—H⋯S inter­actions, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are further linked via N—H⋯S and N—H⋯O hydrogen bonds, forming a two-dimensional network lying parallel to (100). The crystal structure is further stabilized by inter­molecular π–π inter­actions [centroid–centroid distance = 3.7972 (9) Å]. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275013/ /pubmed/22346958 http://dx.doi.org/10.1107/S1600536811056182 Text en © Adabi Ardakani et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Adabi Ardakani, Amir
Kargar, Hadi
Kia, Reza
Tahir, Muhammad Nawaz
(E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
title (E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
title_full (E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
title_fullStr (E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
title_full_unstemmed (E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
title_short (E)-1-(2-Hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
title_sort (e)-1-(2-hy­droxy-5-meth­oxy­benzyl­idene)thio­semicarbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275013/
https://www.ncbi.nlm.nih.gov/pubmed/22346958
http://dx.doi.org/10.1107/S1600536811056182
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