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3,12-Diaza-6,9-diazonia-2,13-dioxotetradecane bis(perchlorate)
The crystal structure of the title diprotonated diacetyltriethylenetetramine (DAT) perchorate salt, C(10)H(24)N(4)O(2) (2+)·2ClO(4) (−), can be described as a three-dimensional assembly of alternating layers consisting of diprotonated diacetyltriethylenetetramine (H(2)DAT)(2+) strands along...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275019/ https://www.ncbi.nlm.nih.gov/pubmed/22346964 http://dx.doi.org/10.1107/S1600536811055516 |
Sumario: | The crystal structure of the title diprotonated diacetyltriethylenetetramine (DAT) perchorate salt, C(10)H(24)N(4)O(2) (2+)·2ClO(4) (−), can be described as a three-dimensional assembly of alternating layers consisting of diprotonated diacetyltriethylenetetramine (H(2)DAT)(2+) strands along [100] and the anionic species ClO(4) (−). The (H(2)DAT)(2+) cations in the strands are connected via N—H⋯O hydrogen bonding between the acetyl groups and the amine groups of neighbouring (H(2)DAT)(2+) cations. Layers of (H(2)DAT)(2+) strands and perchlorate anions are connected by a network of hydrogen bonds between the NH and NH(2) groups and the O atoms of the perchlorate anion. The asymmetric unit consits of one perchlorate anion in a general position, as well as of one cation that is located on a center of inversion. |
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