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3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)

The crystal structure of the title diprotonated diacetyl­triethyl­ene­tetra­mine (DAT) perchorate salt, C(10)H(24)N(4)O(2) (2+)·2ClO(4) (−), can be described as a three-dimensional assembly of alternating layers consisting of diprotonated diacetyl­triethyl­ene­tetra­mine (H(2)DAT)(2+) strands along...

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Autores principales: Söhnel, Tilo, Wichmann, Kathrin A., Doert, Thomas, Cooper, Garth J. S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275019/
https://www.ncbi.nlm.nih.gov/pubmed/22346964
http://dx.doi.org/10.1107/S1600536811055516
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author Söhnel, Tilo
Wichmann, Kathrin A.
Doert, Thomas
Cooper, Garth J. S.
author_facet Söhnel, Tilo
Wichmann, Kathrin A.
Doert, Thomas
Cooper, Garth J. S.
author_sort Söhnel, Tilo
collection PubMed
description The crystal structure of the title diprotonated diacetyl­triethyl­ene­tetra­mine (DAT) perchorate salt, C(10)H(24)N(4)O(2) (2+)·2ClO(4) (−), can be described as a three-dimensional assembly of alternating layers consisting of diprotonated diacetyl­triethyl­ene­tetra­mine (H(2)DAT)(2+) strands along [100] and the anionic species ClO(4) (−). The (H(2)DAT)(2+) cations in the strands are connected via N—H⋯O hydrogen bonding between the acetyl groups and the amine groups of neighbouring (H(2)DAT)(2+) cations. Layers of (H(2)DAT)(2+) strands and perchlorate anions are connected by a network of hydrogen bonds between the NH and NH(2) groups and the O atoms of the perchlorate anion. The asymmetric unit consits of one perchlorate anion in a general position, as well as of one cation that is located on a center of inversion.
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spelling pubmed-32750192012-02-15 3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate) Söhnel, Tilo Wichmann, Kathrin A. Doert, Thomas Cooper, Garth J. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The crystal structure of the title diprotonated diacetyl­triethyl­ene­tetra­mine (DAT) perchorate salt, C(10)H(24)N(4)O(2) (2+)·2ClO(4) (−), can be described as a three-dimensional assembly of alternating layers consisting of diprotonated diacetyl­triethyl­ene­tetra­mine (H(2)DAT)(2+) strands along [100] and the anionic species ClO(4) (−). The (H(2)DAT)(2+) cations in the strands are connected via N—H⋯O hydrogen bonding between the acetyl groups and the amine groups of neighbouring (H(2)DAT)(2+) cations. Layers of (H(2)DAT)(2+) strands and perchlorate anions are connected by a network of hydrogen bonds between the NH and NH(2) groups and the O atoms of the perchlorate anion. The asymmetric unit consits of one perchlorate anion in a general position, as well as of one cation that is located on a center of inversion. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275019/ /pubmed/22346964 http://dx.doi.org/10.1107/S1600536811055516 Text en © Söhnel et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Söhnel, Tilo
Wichmann, Kathrin A.
Doert, Thomas
Cooper, Garth J. S.
3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
title 3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
title_full 3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
title_fullStr 3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
title_full_unstemmed 3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
title_short 3,12-Diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
title_sort 3,12-diaza-6,9-diazo­nia-2,13-dioxotetra­decane bis­(perchlorate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275019/
https://www.ncbi.nlm.nih.gov/pubmed/22346964
http://dx.doi.org/10.1107/S1600536811055516
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