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N-Benzoyl-2-nitro­benzene­sulfonamide

In the title compound, C(13)H(10)N(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn. The mol­ecule is twisted at the S—N bond with a torsion a...

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Autores principales: Suchetan, P. A., Foro, Sabine, Gowda, B. Thimme, Nirmala, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275024/
https://www.ncbi.nlm.nih.gov/pubmed/22346969
http://dx.doi.org/10.1107/S1600536811055917
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author Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
Nirmala, B.
author_facet Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
Nirmala, B.
author_sort Suchetan, P. A.
collection PubMed
description In the title compound, C(13)H(10)N(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn. The mol­ecule is twisted at the S—N bond with a torsion angle of −63.4 (2)°. The sulfonyl benzene ring is tilted by 77.1 (1)° relative to the —SO(2)—NH—C—O segment. The dihedral angle between the sulfonyl and the benzoyl benzene rings is 88.6 (1)°. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link the mol­ecules into inversion dimers, which are linked by weak C—H⋯O and C—H⋯π inter­actions along the b axis.
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spelling pubmed-32750242012-02-15 N-Benzoyl-2-nitro­benzene­sulfonamide Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Nirmala, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)N(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn. The mol­ecule is twisted at the S—N bond with a torsion angle of −63.4 (2)°. The sulfonyl benzene ring is tilted by 77.1 (1)° relative to the —SO(2)—NH—C—O segment. The dihedral angle between the sulfonyl and the benzoyl benzene rings is 88.6 (1)°. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link the mol­ecules into inversion dimers, which are linked by weak C—H⋯O and C—H⋯π inter­actions along the b axis. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275024/ /pubmed/22346969 http://dx.doi.org/10.1107/S1600536811055917 Text en © Suchetan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
Nirmala, B.
N-Benzoyl-2-nitro­benzene­sulfonamide
title N-Benzoyl-2-nitro­benzene­sulfonamide
title_full N-Benzoyl-2-nitro­benzene­sulfonamide
title_fullStr N-Benzoyl-2-nitro­benzene­sulfonamide
title_full_unstemmed N-Benzoyl-2-nitro­benzene­sulfonamide
title_short N-Benzoyl-2-nitro­benzene­sulfonamide
title_sort n-benzoyl-2-nitro­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275024/
https://www.ncbi.nlm.nih.gov/pubmed/22346969
http://dx.doi.org/10.1107/S1600536811055917
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