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N-Benzoyl-2-nitrobenzenesulfonamide
In the title compound, C(13)H(10)N(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn. The molecule is twisted at the S—N bond with a torsion a...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275024/ https://www.ncbi.nlm.nih.gov/pubmed/22346969 http://dx.doi.org/10.1107/S1600536811055917 |
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author | Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Nirmala, B. |
author_facet | Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Nirmala, B. |
author_sort | Suchetan, P. A. |
collection | PubMed |
description | In the title compound, C(13)H(10)N(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn. The molecule is twisted at the S—N bond with a torsion angle of −63.4 (2)°. The sulfonyl benzene ring is tilted by 77.1 (1)° relative to the —SO(2)—NH—C—O segment. The dihedral angle between the sulfonyl and the benzoyl benzene rings is 88.6 (1)°. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link the molecules into inversion dimers, which are linked by weak C—H⋯O and C—H⋯π interactions along the b axis. |
format | Online Article Text |
id | pubmed-3275024 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32750242012-02-15 N-Benzoyl-2-nitrobenzenesulfonamide Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Nirmala, B. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(10)N(2)O(5)S, the N—C bond in the C—SO(2)—NH—C segment has gauche torsion angles with respect to the S=O bonds. The conformation between the N—H bond and the ortho-nitro group in the sulfonyl benzene ring is syn. The molecule is twisted at the S—N bond with a torsion angle of −63.4 (2)°. The sulfonyl benzene ring is tilted by 77.1 (1)° relative to the —SO(2)—NH—C—O segment. The dihedral angle between the sulfonyl and the benzoyl benzene rings is 88.6 (1)°. In the crystal, pairs of N—H⋯O(S) hydrogen bonds link the molecules into inversion dimers, which are linked by weak C—H⋯O and C—H⋯π interactions along the b axis. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275024/ /pubmed/22346969 http://dx.doi.org/10.1107/S1600536811055917 Text en © Suchetan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Nirmala, B. N-Benzoyl-2-nitrobenzenesulfonamide |
title |
N-Benzoyl-2-nitrobenzenesulfonamide |
title_full |
N-Benzoyl-2-nitrobenzenesulfonamide |
title_fullStr |
N-Benzoyl-2-nitrobenzenesulfonamide |
title_full_unstemmed |
N-Benzoyl-2-nitrobenzenesulfonamide |
title_short |
N-Benzoyl-2-nitrobenzenesulfonamide |
title_sort | n-benzoyl-2-nitrobenzenesulfonamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275024/ https://www.ncbi.nlm.nih.gov/pubmed/22346969 http://dx.doi.org/10.1107/S1600536811055917 |
work_keys_str_mv | AT suchetanpa nbenzoyl2nitrobenzenesulfonamide AT forosabine nbenzoyl2nitrobenzenesulfonamide AT gowdabthimme nbenzoyl2nitrobenzenesulfonamide AT nirmalab nbenzoyl2nitrobenzenesulfonamide |