(E)-1-(3-Eth­oxy-2-hy­droxy­benzyl­idene)thio­semicarbazide

The title compound, C(10)H(13)N(3)O(2)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. In the crystal, the A and B mol­ecules are linked via pairs of N—H⋯O and O—H⋯S hydrogen bonds, forming dimers with R (2) (2)(14) and R (2) (2)(6) ring motifs. These dimers are link...

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Detalles Bibliográficos
Autores principales: Adabi Ardakani, Amir, Kargar, Hadi, Kia, Reza, Tahir, Muhammad Nawaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275025/
https://www.ncbi.nlm.nih.gov/pubmed/22346970
http://dx.doi.org/10.1107/S1600536812000487
Descripción
Sumario:The title compound, C(10)H(13)N(3)O(2)S, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. In the crystal, the A and B mol­ecules are linked via pairs of N—H⋯O and O—H⋯S hydrogen bonds, forming dimers with R (2) (2)(14) and R (2) (2)(6) ring motifs. These dimers are linked via a pair of N—H⋯S hydrogen bonds with an R (2) (2)(8) ring motif, forming chains propagating along the c-axis direction. The crystal was refined as an inversion twin with a final BASF ratio of 0.54 (11):0.46 (11).

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