1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione

The title compound, C(20)H(17)N(3)O(2)S(2), crystallizes with two mol­ecules in the asymmetric unit. The pyrrolo­dine rings have envelope conformations in both mol­ecules, the N atoms deviating by 0.574 (3) and 0.612 (2) Å from the mean planes through the other ring atoms. The 1′-methyl and 4′-pheny...

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Detalles Bibliográficos
Autores principales: Natarajan, Sampath, Mathews, Rita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275027/
https://www.ncbi.nlm.nih.gov/pubmed/22346972
http://dx.doi.org/10.1107/S1600536811056236
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author Natarajan, Sampath
Mathews, Rita
author_facet Natarajan, Sampath
Mathews, Rita
author_sort Natarajan, Sampath
collection PubMed
description The title compound, C(20)H(17)N(3)O(2)S(2), crystallizes with two mol­ecules in the asymmetric unit. The pyrrolo­dine rings have envelope conformations in both mol­ecules, the N atoms deviating by 0.574 (3) and 0.612 (2) Å from the mean planes through the other ring atoms. The 1′-methyl and 4′-phenyl groups on the pyrrolidine rings are substituted in equatorial positions. In the crystal, mol­ecules are linked into a three-dimensional network by N—H⋯O, N—H⋯N and C—H⋯O and N—H⋯π hydrogen bonds.
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spelling pubmed-32750272012-02-15 1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione Natarajan, Sampath Mathews, Rita Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(17)N(3)O(2)S(2), crystallizes with two mol­ecules in the asymmetric unit. The pyrrolo­dine rings have envelope conformations in both mol­ecules, the N atoms deviating by 0.574 (3) and 0.612 (2) Å from the mean planes through the other ring atoms. The 1′-methyl and 4′-phenyl groups on the pyrrolidine rings are substituted in equatorial positions. In the crystal, mol­ecules are linked into a three-dimensional network by N—H⋯O, N—H⋯N and C—H⋯O and N—H⋯π hydrogen bonds. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275027/ /pubmed/22346972 http://dx.doi.org/10.1107/S1600536811056236 Text en © Natarajan and Mathews 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Natarajan, Sampath
Mathews, Rita
1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
title 1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
title_full 1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
title_fullStr 1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
title_full_unstemmed 1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
title_short 1′-Methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
title_sort 1′-methyl-4′-phenyl-2′′-sulfanylidene­dispiro­[indoline-3,2′-pyrrolidine-3′,5′′-1,3-thia­zolidine]-2,4′′-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275027/
https://www.ncbi.nlm.nih.gov/pubmed/22346972
http://dx.doi.org/10.1107/S1600536811056236
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