1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one

In the title benzimidazolone, C(27)H(38)N(2)O(11), which has N-bound glycosidic units, all five-membered O-heterocyclic rings adopt envelope conformations [for the outer rings, the C atom with the dimethyl groups represents the flap atom]. The two glycosidic units are related by a non-crystallograph...

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Autores principales: Lakhrissi, Brahim, Massoui, Mohamed, Ramli, Youssef, Essassi, El Mokhtar, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275034/
https://www.ncbi.nlm.nih.gov/pubmed/22346979
http://dx.doi.org/10.1107/S160053681105625X
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author Lakhrissi, Brahim
Massoui, Mohamed
Ramli, Youssef
Essassi, El Mokhtar
Ng, Seik Weng
author_facet Lakhrissi, Brahim
Massoui, Mohamed
Ramli, Youssef
Essassi, El Mokhtar
Ng, Seik Weng
author_sort Lakhrissi, Brahim
collection PubMed
description In the title benzimidazolone, C(27)H(38)N(2)O(11), which has N-bound glycosidic units, all five-membered O-heterocyclic rings adopt envelope conformations [for the outer rings, the C atom with the dimethyl groups represents the flap atom]. The two glycosidic units are related by a non-crystallographic twofold rotation axis that passes through the carbonyl portion. In the mol­ecular structure, the hy­droxy groups are hydrogen-bond donors to the carbonyl O atom. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure.
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spelling pubmed-32750342012-02-15 1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one Lakhrissi, Brahim Massoui, Mohamed Ramli, Youssef Essassi, El Mokhtar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title benzimidazolone, C(27)H(38)N(2)O(11), which has N-bound glycosidic units, all five-membered O-heterocyclic rings adopt envelope conformations [for the outer rings, the C atom with the dimethyl groups represents the flap atom]. The two glycosidic units are related by a non-crystallographic twofold rotation axis that passes through the carbonyl portion. In the mol­ecular structure, the hy­droxy groups are hydrogen-bond donors to the carbonyl O atom. Weak inter­molecular C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275034/ /pubmed/22346979 http://dx.doi.org/10.1107/S160053681105625X Text en © Lakhrissi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lakhrissi, Brahim
Massoui, Mohamed
Ramli, Youssef
Essassi, El Mokhtar
Ng, Seik Weng
1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one
title 1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one
title_full 1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one
title_fullStr 1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one
title_full_unstemmed 1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one
title_short 1,3-Bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2H-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1H-1,3-benzodiazol-2-one
title_sort 1,3-bis[2-hy­droxy-2-(6-meth­oxy-2,2-dimethyl-3a,5,6,6a-tetra­hydro-2h-furo[2,3-d][1,3]dioxol-5-yl)eth­yl]-2,3-dihydro-1h-1,3-benzodiazol-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275034/
https://www.ncbi.nlm.nih.gov/pubmed/22346979
http://dx.doi.org/10.1107/S160053681105625X
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