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(2E,6E)-2,6-Bis(4-methylbenzylidene)cyclohex-3-en-1-one
The title compound, C(22)H(20)O, shows an approximately planar cyclohexenone ring [maximum deviation = 0.069 (4) Å], with a disordered position of the C=C bond [ratio = 0.71 (2)/0.29 (2)]. The benzene rings of the 4-methylbenzylidene units, attached in the 2- and 6-positions to the cyclohexenone...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275037/ https://www.ncbi.nlm.nih.gov/pubmed/22346982 http://dx.doi.org/10.1107/S1600536811055632 |
Sumario: | The title compound, C(22)H(20)O, shows an approximately planar cyclohexenone ring [maximum deviation = 0.069 (4) Å], with a disordered position of the C=C bond [ratio = 0.71 (2)/0.29 (2)]. The benzene rings of the 4-methylbenzylidene units, attached in the 2- and 6-positions to the cyclohexenone ring, are rotated in the same direction by 28.6 (4) and 22.4 (4)°, with respect to the mean plane of the cyclohexenone ring [fraction 0.71 (2); maximum deviation = 0.06 (3) Å]. In the crystal, molecules are packed in the manner of a distorted hexagonal rod packing with their long axes all aligned along [201]. A number of C—H⋯π interactions stablize the crystal structure. |
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