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(4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one

The title compound, C(22)H(22)O(5), crystallizes with two independent mol­ecules in the asymmetric unit, both of which possess pseudo-C (s) symmetry. The central 1,3-dioxanone rings have envelope conformations, with the C atom bearing the two methyl groups at the flap. The benzene rings of the meth­...

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Detalles Bibliográficos
Autores principales: Mojtahedi, Mohammad M., Massa, Werner, Abaee, M. Saeed, Mesbah, A. Wahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275038/
https://www.ncbi.nlm.nih.gov/pubmed/22346983
http://dx.doi.org/10.1107/S1600536812000372
Descripción
Sumario:The title compound, C(22)H(22)O(5), crystallizes with two independent mol­ecules in the asymmetric unit, both of which possess pseudo-C (s) symmetry. The central 1,3-dioxanone rings have envelope conformations, with the C atom bearing the two methyl groups at the flap. The benzene rings of the meth­oxy­benzyl­idene units, attached in the 4- and 6-positions on the central 1,3-dioxanone rings, are tilted in the same direction with dihedral angles varying between 8.2 (1) and 18.1 (1)°. The crystal packing is influenced by π-stacking inter­actions of the parallel displaced type [centroid–centroid distance of 3.723 (1) Å for mol­ecule 1 and 3.884 (1) Å for mol­ecule 2, with ring slippages of 1.432 and 1.613 Å, respectively] and the T-shaped type, with the long mol­ecular axes all aligned along [010].