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(4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one

The title compound, C(22)H(22)O(5), crystallizes with two independent mol­ecules in the asymmetric unit, both of which possess pseudo-C (s) symmetry. The central 1,3-dioxanone rings have envelope conformations, with the C atom bearing the two methyl groups at the flap. The benzene rings of the meth­...

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Autores principales: Mojtahedi, Mohammad M., Massa, Werner, Abaee, M. Saeed, Mesbah, A. Wahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275038/
https://www.ncbi.nlm.nih.gov/pubmed/22346983
http://dx.doi.org/10.1107/S1600536812000372
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author Mojtahedi, Mohammad M.
Massa, Werner
Abaee, M. Saeed
Mesbah, A. Wahid
author_facet Mojtahedi, Mohammad M.
Massa, Werner
Abaee, M. Saeed
Mesbah, A. Wahid
author_sort Mojtahedi, Mohammad M.
collection PubMed
description The title compound, C(22)H(22)O(5), crystallizes with two independent mol­ecules in the asymmetric unit, both of which possess pseudo-C (s) symmetry. The central 1,3-dioxanone rings have envelope conformations, with the C atom bearing the two methyl groups at the flap. The benzene rings of the meth­oxy­benzyl­idene units, attached in the 4- and 6-positions on the central 1,3-dioxanone rings, are tilted in the same direction with dihedral angles varying between 8.2 (1) and 18.1 (1)°. The crystal packing is influenced by π-stacking inter­actions of the parallel displaced type [centroid–centroid distance of 3.723 (1) Å for mol­ecule 1 and 3.884 (1) Å for mol­ecule 2, with ring slippages of 1.432 and 1.613 Å, respectively] and the T-shaped type, with the long mol­ecular axes all aligned along [010].
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spelling pubmed-32750382012-02-15 (4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one Mojtahedi, Mohammad M. Massa, Werner Abaee, M. Saeed Mesbah, A. Wahid Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(22)O(5), crystallizes with two independent mol­ecules in the asymmetric unit, both of which possess pseudo-C (s) symmetry. The central 1,3-dioxanone rings have envelope conformations, with the C atom bearing the two methyl groups at the flap. The benzene rings of the meth­oxy­benzyl­idene units, attached in the 4- and 6-positions on the central 1,3-dioxanone rings, are tilted in the same direction with dihedral angles varying between 8.2 (1) and 18.1 (1)°. The crystal packing is influenced by π-stacking inter­actions of the parallel displaced type [centroid–centroid distance of 3.723 (1) Å for mol­ecule 1 and 3.884 (1) Å for mol­ecule 2, with ring slippages of 1.432 and 1.613 Å, respectively] and the T-shaped type, with the long mol­ecular axes all aligned along [010]. International Union of Crystallography 2012-01-11 /pmc/articles/PMC3275038/ /pubmed/22346983 http://dx.doi.org/10.1107/S1600536812000372 Text en © Mojtahedi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mojtahedi, Mohammad M.
Massa, Werner
Abaee, M. Saeed
Mesbah, A. Wahid
(4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
title (4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
title_full (4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
title_fullStr (4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
title_full_unstemmed (4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
title_short (4Z,6Z)-4,6-Bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
title_sort (4z,6z)-4,6-bis(4-meth­oxy­benzyl­idene)-2,2-dimethyl-1,3-dioxan-5-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275038/
https://www.ncbi.nlm.nih.gov/pubmed/22346983
http://dx.doi.org/10.1107/S1600536812000372
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