Cargando…
2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide
Two molecules make up the asymmetric unit of the title compound, C(12)H(18)N(4)O(2), and both feature an intramolecular O—H⋯N hydrogen bond, which generates an S(6) ring. The diethylamino group of one of the molecules is disordered over two sets of sites in a 0.59 (2):0.41 (2) ratio. In the crys...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275058/ https://www.ncbi.nlm.nih.gov/pubmed/22347003 http://dx.doi.org/10.1107/S1600536812000311 |
_version_ | 1782223166339284992 |
---|---|
author | Fun, Hoong-Kun Ooi, Chin Wei Malladi, Shridhar Isloor, Arun M. Shivananda, Kammasandra N. |
author_facet | Fun, Hoong-Kun Ooi, Chin Wei Malladi, Shridhar Isloor, Arun M. Shivananda, Kammasandra N. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | Two molecules make up the asymmetric unit of the title compound, C(12)H(18)N(4)O(2), and both feature an intramolecular O—H⋯N hydrogen bond, which generates an S(6) ring. The diethylamino group of one of the molecules is disordered over two sets of sites in a 0.59 (2):0.41 (2) ratio. In the crystal, N—H⋯O hydrogen bonds link the molecules into sheets lying parallel to the ac plane and C—H⋯π interactions are also observed. |
format | Online Article Text |
id | pubmed-3275058 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32750582012-02-15 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide Fun, Hoong-Kun Ooi, Chin Wei Malladi, Shridhar Isloor, Arun M. Shivananda, Kammasandra N. Acta Crystallogr Sect E Struct Rep Online Organic Papers Two molecules make up the asymmetric unit of the title compound, C(12)H(18)N(4)O(2), and both feature an intramolecular O—H⋯N hydrogen bond, which generates an S(6) ring. The diethylamino group of one of the molecules is disordered over two sets of sites in a 0.59 (2):0.41 (2) ratio. In the crystal, N—H⋯O hydrogen bonds link the molecules into sheets lying parallel to the ac plane and C—H⋯π interactions are also observed. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275058/ /pubmed/22347003 http://dx.doi.org/10.1107/S1600536812000311 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Ooi, Chin Wei Malladi, Shridhar Isloor, Arun M. Shivananda, Kammasandra N. 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
title | 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
title_full | 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
title_fullStr | 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
title_full_unstemmed | 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
title_short | 2-[(E)-4-Diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
title_sort | 2-[(e)-4-diethylamino-2-hydroxybenzylidene]hydrazinecarboxamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275058/ https://www.ncbi.nlm.nih.gov/pubmed/22347003 http://dx.doi.org/10.1107/S1600536812000311 |
work_keys_str_mv | AT funhoongkun 2e4diethylamino2hydroxybenzylidenehydrazinecarboxamide AT ooichinwei 2e4diethylamino2hydroxybenzylidenehydrazinecarboxamide AT malladishridhar 2e4diethylamino2hydroxybenzylidenehydrazinecarboxamide AT isloorarunm 2e4diethylamino2hydroxybenzylidenehydrazinecarboxamide AT shivanandakammasandran 2e4diethylamino2hydroxybenzylidenehydrazinecarboxamide |