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Benzoic acid–3,4-bis[(pyridin-3-ylmethyl)amino]cyclobut-3-ene-1,2-dione (1/2)
In the title co-crystal, C(16)H(14)N(4)O(2)·2C(7)H(6)O(2), the 3,4-bis[(pyridin-3-ylmethyl)amino]cyclobut-3-ene-1,2-dione squareamide molecules assemble into chains along the b axis via N—H⋯O hydrogen bonds. The benzoic acid molecules then hydrogen bond to the pyridine rings via O—H⋯N hydrogen...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275061/ https://www.ncbi.nlm.nih.gov/pubmed/22347006 http://dx.doi.org/10.1107/S1600536812000220 |
Sumario: | In the title co-crystal, C(16)H(14)N(4)O(2)·2C(7)H(6)O(2), the 3,4-bis[(pyridin-3-ylmethyl)amino]cyclobut-3-ene-1,2-dione squareamide molecules assemble into chains along the b axis via N—H⋯O hydrogen bonds. The benzoic acid molecules then hydrogen bond to the pyridine rings via O—H⋯N hydrogen bonds, supported by weaker C—H⋯O hydrogen bonds, forming extended ribbons. The asymmetric unit consists of a half squareamide molecule, sitting on a special position around a twofold axis, and one benzoic acid molecule on a general position. |
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