Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)

In the title co-crystal, C(16)H(14)N(4)O(2)·2C(7)H(6)O(2), the 3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione squareamide mol­ecules assemble into chains along the b axis via N—H⋯O hydrogen bonds. The benzoic acid mol­ecules then hydrogen bond to the pyridine rings via O—H⋯N hydrogen...

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Detalles Bibliográficos
Autores principales: Lemmerer, Andreas, Bourne, Susan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275061/
https://www.ncbi.nlm.nih.gov/pubmed/22347006
http://dx.doi.org/10.1107/S1600536812000220
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author Lemmerer, Andreas
Bourne, Susan A.
author_facet Lemmerer, Andreas
Bourne, Susan A.
author_sort Lemmerer, Andreas
collection PubMed
description In the title co-crystal, C(16)H(14)N(4)O(2)·2C(7)H(6)O(2), the 3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione squareamide mol­ecules assemble into chains along the b axis via N—H⋯O hydrogen bonds. The benzoic acid mol­ecules then hydrogen bond to the pyridine rings via O—H⋯N hydrogen bonds, supported by weaker C—H⋯O hydrogen bonds, forming extended ribbons. The asymmetric unit consists of a half squareamide mol­ecule, sitting on a special position around a twofold axis, and one benzoic acid mol­ecule on a general position.
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spelling pubmed-32750612012-02-15 Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2) Lemmerer, Andreas Bourne, Susan A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title co-crystal, C(16)H(14)N(4)O(2)·2C(7)H(6)O(2), the 3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione squareamide mol­ecules assemble into chains along the b axis via N—H⋯O hydrogen bonds. The benzoic acid mol­ecules then hydrogen bond to the pyridine rings via O—H⋯N hydrogen bonds, supported by weaker C—H⋯O hydrogen bonds, forming extended ribbons. The asymmetric unit consists of a half squareamide mol­ecule, sitting on a special position around a twofold axis, and one benzoic acid mol­ecule on a general position. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275061/ /pubmed/22347006 http://dx.doi.org/10.1107/S1600536812000220 Text en © Lemmerer and Bourne 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lemmerer, Andreas
Bourne, Susan A.
Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
title Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
title_full Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
title_fullStr Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
title_full_unstemmed Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
title_short Benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
title_sort benzoic acid–3,4-bis­[(pyridin-3-ylmeth­yl)amino]­cyclo­but-3-ene-1,2-dione (1/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275061/
https://www.ncbi.nlm.nih.gov/pubmed/22347006
http://dx.doi.org/10.1107/S1600536812000220
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