Cargando…
3-Fluoro-12H-benzimidazo[2,1-b][1,3]benzothiazin-12-one
In the title compound, C(14)H(7)FN(2)OS, prepared by the reaction of 2-bromo-4-fluorobenzoyl choride with 2-mercaptobenzimidazole, the four-membered fused-ring system is essentially planar [maximum deviation from the mean plane = 0.035 (2) Å]. The crystal packing is stabilized by weak intermolecul...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275067/ https://www.ncbi.nlm.nih.gov/pubmed/22347012 http://dx.doi.org/10.1107/S1600536811054948 |
Sumario: | In the title compound, C(14)H(7)FN(2)OS, prepared by the reaction of 2-bromo-4-fluorobenzoyl choride with 2-mercaptobenzimidazole, the four-membered fused-ring system is essentially planar [maximum deviation from the mean plane = 0.035 (2) Å]. The crystal packing is stabilized by weak intermolecular π–π [minimum ring centroid–centroid separation = 3.509 (7) Å], weak C—F⋯π [F⋯centroid = 3.4464 (17) Å, C—F⋯centroid = 97.72 (11)°] and C—O⋯π [O⋯centroid = 3.5230 (16) and 3.7296 (17) Å, C—O⋯centroid = 86.40 (10) and 86.25 (10)°] interactions and weak intermolecular C—H⋯N hydrogen bonds. |
---|