1-Benzoyl-2-thio­biuret

In the title compound [systematic name: N-(carbamoyl­carb­a­mo­thio­yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral a...

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Detalles Bibliográficos
Autores principales: Kang, Sung Kwon, Cho, Nam Sook, Jeon, Min Kyeong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275072/
https://www.ncbi.nlm.nih.gov/pubmed/22347017
http://dx.doi.org/10.1107/S1600536812000621
Descripción
Sumario:In the title compound [systematic name: N-(carbamoyl­carb­a­mo­thio­yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral angle of 8.48 (5)°. The mol­ecular structure is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, N—H⋯O and N—H⋯S hydrogen bonds link the mol­ecules into a sheet parallel to the bc plane.

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