1-Benzoyl-2-thio­biuret

In the title compound [systematic name: N-(carbamoyl­carb­a­mo­thio­yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral a...

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Detalles Bibliográficos
Autores principales: Kang, Sung Kwon, Cho, Nam Sook, Jeon, Min Kyeong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275072/
https://www.ncbi.nlm.nih.gov/pubmed/22347017
http://dx.doi.org/10.1107/S1600536812000621
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author Kang, Sung Kwon
Cho, Nam Sook
Jeon, Min Kyeong
author_facet Kang, Sung Kwon
Cho, Nam Sook
Jeon, Min Kyeong
author_sort Kang, Sung Kwon
collection PubMed
description In the title compound [systematic name: N-(carbamoyl­carb­a­mo­thio­yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral angle of 8.48 (5)°. The mol­ecular structure is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, N—H⋯O and N—H⋯S hydrogen bonds link the mol­ecules into a sheet parallel to the bc plane.
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spelling pubmed-32750722012-02-15 1-Benzoyl-2-thio­biuret Kang, Sung Kwon Cho, Nam Sook Jeon, Min Kyeong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound [systematic name: N-(carbamoyl­carb­a­mo­thio­yl)benzamide], C(9)H(9)N(3)O(2)S, the benzoyl and terminal urea fragments adopt cisoid and transoid conformations, respectively, with respect to the S atom. The benzoyl and thio­biuret groups are almost coplanar, making a dihedral angle of 8.48 (5)°. The mol­ecular structure is stabilized by an intra­molecular N—H⋯O hydrogen bond. In the crystal, N—H⋯O and N—H⋯S hydrogen bonds link the mol­ecules into a sheet parallel to the bc plane. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275072/ /pubmed/22347017 http://dx.doi.org/10.1107/S1600536812000621 Text en © Kang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kang, Sung Kwon
Cho, Nam Sook
Jeon, Min Kyeong
1-Benzoyl-2-thio­biuret
title 1-Benzoyl-2-thio­biuret
title_full 1-Benzoyl-2-thio­biuret
title_fullStr 1-Benzoyl-2-thio­biuret
title_full_unstemmed 1-Benzoyl-2-thio­biuret
title_short 1-Benzoyl-2-thio­biuret
title_sort 1-benzoyl-2-thio­biuret
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275072/
https://www.ncbi.nlm.nih.gov/pubmed/22347017
http://dx.doi.org/10.1107/S1600536812000621
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AT chonamsook 1benzoyl2thiobiuret
AT jeonminkyeong 1benzoyl2thiobiuret

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