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(1R,2R,E,E)-N,N′-Bis(4-chlorobenzylidene)cyclohexane-1,2-diamine
The title Schiff base ligand, C(20)H(20)Cl(2)N(2), was prepared by condensation of commercially available p-chlorobenzaldehyde and (R,R)-1,2-diammoniumcyclohexane mono-(+)-tartrate. The cyclohexane ring adopts a chair conformation. The dihedral angle between the two aromatic rings is 62.52 (8)°...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275080/ https://www.ncbi.nlm.nih.gov/pubmed/22347025 http://dx.doi.org/10.1107/S1600536812000724 |
Sumario: | The title Schiff base ligand, C(20)H(20)Cl(2)N(2), was prepared by condensation of commercially available p-chlorobenzaldehyde and (R,R)-1,2-diammoniumcyclohexane mono-(+)-tartrate. The cyclohexane ring adopts a chair conformation. The dihedral angle between the two aromatic rings is 62.52 (8)°. The crystal structure is stabilized by an intermolecular C—H⋯Cl hydrogen bond. |
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