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N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide

There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C—N—N—C torsion angl...

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Detalles Bibliográficos
Autores principales: Bikas, Rahman, Anarjan, Parisa Mahboubi, Aslekhademi, Sanam, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275172/
https://www.ncbi.nlm.nih.gov/pubmed/22347028
http://dx.doi.org/10.1107/S1600536812000529
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author Bikas, Rahman
Anarjan, Parisa Mahboubi
Aslekhademi, Sanam
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Bikas, Rahman
Anarjan, Parisa Mahboubi
Aslekhademi, Sanam
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Bikas, Rahman
collection PubMed
description There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C—N—N—C torsion angle is −138.25 (13)°]. The conformation about the ethene bond is Z. An intra­molecular N—H⋯O hydrogen bond involving the benzoyl O atom and leading to an S(6) motif is formed. Significant delocalization of π-electron density is found in this part of the mol­ecule. In the crystal, helical supra­molecular chains aligned along the b axis and mediated by N—H⋯O hydrogen bonds are formed.
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spelling pubmed-32751722012-02-15 N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide Bikas, Rahman Anarjan, Parisa Mahboubi Aslekhademi, Sanam Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C—N—N—C torsion angle is −138.25 (13)°]. The conformation about the ethene bond is Z. An intra­molecular N—H⋯O hydrogen bond involving the benzoyl O atom and leading to an S(6) motif is formed. Significant delocalization of π-electron density is found in this part of the mol­ecule. In the crystal, helical supra­molecular chains aligned along the b axis and mediated by N—H⋯O hydrogen bonds are formed. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275172/ /pubmed/22347028 http://dx.doi.org/10.1107/S1600536812000529 Text en © Bikas et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bikas, Rahman
Anarjan, Parisa Mahboubi
Aslekhademi, Sanam
Ng, Seik Weng
Tiekink, Edward R. T.
N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
title N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
title_full N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
title_fullStr N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
title_full_unstemmed N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
title_short N′-[(2Z)-4-Oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
title_sort n′-[(2z)-4-oxo-4-phenyl­but-2-en-2-yl]pyridine-4-carbohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275172/
https://www.ncbi.nlm.nih.gov/pubmed/22347028
http://dx.doi.org/10.1107/S1600536812000529
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