Cargando…
N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide
There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C—N—N—C torsion angl...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275172/ https://www.ncbi.nlm.nih.gov/pubmed/22347028 http://dx.doi.org/10.1107/S1600536812000529 |
_version_ | 1782223177350381568 |
---|---|
author | Bikas, Rahman Anarjan, Parisa Mahboubi Aslekhademi, Sanam Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Bikas, Rahman Anarjan, Parisa Mahboubi Aslekhademi, Sanam Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Bikas, Rahman |
collection | PubMed |
description | There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C—N—N—C torsion angle is −138.25 (13)°]. The conformation about the ethene bond is Z. An intramolecular N—H⋯O hydrogen bond involving the benzoyl O atom and leading to an S(6) motif is formed. Significant delocalization of π-electron density is found in this part of the molecule. In the crystal, helical supramolecular chains aligned along the b axis and mediated by N—H⋯O hydrogen bonds are formed. |
format | Online Article Text |
id | pubmed-3275172 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32751722012-02-15 N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide Bikas, Rahman Anarjan, Parisa Mahboubi Aslekhademi, Sanam Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers There are significant twists in the title compound, C(16)H(15)N(3)O(2), as seen in the dihedral angle between the benzene and adjacent but-2-enal group [29.26 (4)°] and between the pyridine ring and amide group [24.79 (6)°]. A twist is also evident around the hydrazine bond [the C—N—N—C torsion angle is −138.25 (13)°]. The conformation about the ethene bond is Z. An intramolecular N—H⋯O hydrogen bond involving the benzoyl O atom and leading to an S(6) motif is formed. Significant delocalization of π-electron density is found in this part of the molecule. In the crystal, helical supramolecular chains aligned along the b axis and mediated by N—H⋯O hydrogen bonds are formed. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275172/ /pubmed/22347028 http://dx.doi.org/10.1107/S1600536812000529 Text en © Bikas et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bikas, Rahman Anarjan, Parisa Mahboubi Aslekhademi, Sanam Ng, Seik Weng Tiekink, Edward R. T. N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
title |
N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
title_full |
N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
title_fullStr |
N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
title_full_unstemmed |
N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
title_short |
N′-[(2Z)-4-Oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
title_sort | n′-[(2z)-4-oxo-4-phenylbut-2-en-2-yl]pyridine-4-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275172/ https://www.ncbi.nlm.nih.gov/pubmed/22347028 http://dx.doi.org/10.1107/S1600536812000529 |
work_keys_str_mv | AT bikasrahman n2z4oxo4phenylbut2en2ylpyridine4carbohydrazide AT anarjanparisamahboubi n2z4oxo4phenylbut2en2ylpyridine4carbohydrazide AT aslekhademisanam n2z4oxo4phenylbut2en2ylpyridine4carbohydrazide AT ngseikweng n2z4oxo4phenylbut2en2ylpyridine4carbohydrazide AT tiekinkedwardrt n2z4oxo4phenylbut2en2ylpyridine4carbohydrazide |