Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate

In the title compound, C(25)H(25)NO(5)S, the O atom of the hy­droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy­droxy­methyl­benzene and phenyl rings. T...

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Detalles Bibliográficos
Autores principales: Madhanraj, R., Murugavel, S., Kannan, D., Bakthadoss, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275177/
https://www.ncbi.nlm.nih.gov/pubmed/22347033
http://dx.doi.org/10.1107/S1600536812000864
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author Madhanraj, R.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_facet Madhanraj, R.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
author_sort Madhanraj, R.
collection PubMed
description In the title compound, C(25)H(25)NO(5)S, the O atom of the hy­droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy­droxy­methyl­benzene and phenyl rings. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-32751772012-02-15 Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate Madhanraj, R. Murugavel, S. Kannan, D. Bakthadoss, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(25)NO(5)S, the O atom of the hy­droxy group is disordered over two positions, with occupancies of 0.820 (2) and 0.180 (2). The sulfonyl-bound benzene ring forms dihedral angles of 31.8 (1) and 60.7 (1)°, respectively, with the hy­droxy­methyl­benzene and phenyl rings. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯O hydrogen bond, generating an S(8) ring motif. The crystal packing is stabilized by inter­molecular C—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2012-01-14 /pmc/articles/PMC3275177/ /pubmed/22347033 http://dx.doi.org/10.1107/S1600536812000864 Text en © Madhanraj et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Madhanraj, R.
Murugavel, S.
Kannan, D.
Bakthadoss, M.
Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
title Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
title_full Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
title_fullStr Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
title_full_unstemmed Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
title_short Methyl (2Z)-2-({N-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
title_sort methyl (2z)-2-({n-[2-(hy­droxy­meth­yl)phen­yl]-4-methyl­benzene­sulfonamido}­meth­yl)-3-phenyl­prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275177/
https://www.ncbi.nlm.nih.gov/pubmed/22347033
http://dx.doi.org/10.1107/S1600536812000864
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AT murugavels methyl2z2n2hydroxymethylphenyl4methylbenzenesulfonamidomethyl3phenylprop2enoate
AT kannand methyl2z2n2hydroxymethylphenyl4methylbenzenesulfonamidomethyl3phenylprop2enoate
AT bakthadossm methyl2z2n2hydroxymethylphenyl4methylbenzenesulfonamidomethyl3phenylprop2enoate

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