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2-(Thiophen-2-yl)-1-(thiophen-2-ylmethyl)-1H-benzimidazole
In the title compound, C(16)H(12)N(2)S(2), the thiophene groups are rotationally disordered over two sets of sites, by approximately 180°, with occupancy ratios of 0.916 (2):0.084 (2) and 0.903 (2):0.097 (2). The major components of the thiophene and methylene substituted thiophene rings are can...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275178/ https://www.ncbi.nlm.nih.gov/pubmed/22347034 http://dx.doi.org/10.1107/S1600536811055103 |
Sumario: | In the title compound, C(16)H(12)N(2)S(2), the thiophene groups are rotationally disordered over two sets of sites, by approximately 180°, with occupancy ratios of 0.916 (2):0.084 (2) and 0.903 (2):0.097 (2). The major components of the thiophene and methylene substituted thiophene rings are canted by 24.06 (12) and 85.07 (10)°, respectively, from the benzimidazole ring system plane and the dihedral angle between the major component thiophene ring planes is 84.90 (14)°. In the crystal, there is a weak C—H⋯N hydrogen bond which links molecules into chains. |
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