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Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)

In the title compound, C(3)H(12)N(2) (2+)·2BF(4) (−)·2C(12)H(24)O(6), the central C atom of the propane-1,3-diammonium cation lies on a crystallographic twofold rotation axis. The terminal NH(3) (+) groups insert into the crown rings through strong N—H⋯O hydrogen-bonding inter­actions, resulting in...

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Detalles Bibliográficos
Autor principal: Zhao, Min-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275199/
https://www.ncbi.nlm.nih.gov/pubmed/22347055
http://dx.doi.org/10.1107/S1600536812001572
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author Zhao, Min-Min
author_facet Zhao, Min-Min
author_sort Zhao, Min-Min
collection PubMed
description In the title compound, C(3)H(12)N(2) (2+)·2BF(4) (−)·2C(12)H(24)O(6), the central C atom of the propane-1,3-diammonium cation lies on a crystallographic twofold rotation axis. The terminal NH(3) (+) groups insert into the crown rings through strong N—H⋯O hydrogen-bonding inter­actions, resulting in the formation of a 1:2 supra­molecular [(C(3)H(12)N(2))·(C(12)H(24)O(6))(2)](2+) complex. The anions are linked to the supra­molecular complexes via weak C—H⋯F hydrogen bonds. The F atoms of the anion are disordered over two orientations with site occupancies of 0.5.
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spelling pubmed-32751992012-02-15 Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2) Zhao, Min-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(3)H(12)N(2) (2+)·2BF(4) (−)·2C(12)H(24)O(6), the central C atom of the propane-1,3-diammonium cation lies on a crystallographic twofold rotation axis. The terminal NH(3) (+) groups insert into the crown rings through strong N—H⋯O hydrogen-bonding inter­actions, resulting in the formation of a 1:2 supra­molecular [(C(3)H(12)N(2))·(C(12)H(24)O(6))(2)](2+) complex. The anions are linked to the supra­molecular complexes via weak C—H⋯F hydrogen bonds. The F atoms of the anion are disordered over two orientations with site occupancies of 0.5. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3275199/ /pubmed/22347055 http://dx.doi.org/10.1107/S1600536812001572 Text en © Min-Min Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Min-Min
Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
title Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
title_full Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
title_fullStr Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
title_full_unstemmed Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
title_short Propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
title_sort propane-1,3-diaminium bis­(tetra­fluoro­borate)–18-crown-6 (1/2)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275199/
https://www.ncbi.nlm.nih.gov/pubmed/22347055
http://dx.doi.org/10.1107/S1600536812001572
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