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Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2)
In the title compound, C(3)H(12)N(2) (2+)·2BF(4) (−)·2C(12)H(24)O(6), the central C atom of the propane-1,3-diammonium cation lies on a crystallographic twofold rotation axis. The terminal NH(3) (+) groups insert into the crown rings through strong N—H⋯O hydrogen-bonding interactions, resulting in...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275199/ https://www.ncbi.nlm.nih.gov/pubmed/22347055 http://dx.doi.org/10.1107/S1600536812001572 |
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author | Zhao, Min-Min |
author_facet | Zhao, Min-Min |
author_sort | Zhao, Min-Min |
collection | PubMed |
description | In the title compound, C(3)H(12)N(2) (2+)·2BF(4) (−)·2C(12)H(24)O(6), the central C atom of the propane-1,3-diammonium cation lies on a crystallographic twofold rotation axis. The terminal NH(3) (+) groups insert into the crown rings through strong N—H⋯O hydrogen-bonding interactions, resulting in the formation of a 1:2 supramolecular [(C(3)H(12)N(2))·(C(12)H(24)O(6))(2)](2+) complex. The anions are linked to the supramolecular complexes via weak C—H⋯F hydrogen bonds. The F atoms of the anion are disordered over two orientations with site occupancies of 0.5. |
format | Online Article Text |
id | pubmed-3275199 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32751992012-02-15 Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) Zhao, Min-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(3)H(12)N(2) (2+)·2BF(4) (−)·2C(12)H(24)O(6), the central C atom of the propane-1,3-diammonium cation lies on a crystallographic twofold rotation axis. The terminal NH(3) (+) groups insert into the crown rings through strong N—H⋯O hydrogen-bonding interactions, resulting in the formation of a 1:2 supramolecular [(C(3)H(12)N(2))·(C(12)H(24)O(6))(2)](2+) complex. The anions are linked to the supramolecular complexes via weak C—H⋯F hydrogen bonds. The F atoms of the anion are disordered over two orientations with site occupancies of 0.5. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3275199/ /pubmed/22347055 http://dx.doi.org/10.1107/S1600536812001572 Text en © Min-Min Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhao, Min-Min Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
title | Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
title_full | Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
title_fullStr | Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
title_full_unstemmed | Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
title_short | Propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
title_sort | propane-1,3-diaminium bis(tetrafluoroborate)–18-crown-6 (1/2) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275199/ https://www.ncbi.nlm.nih.gov/pubmed/22347055 http://dx.doi.org/10.1107/S1600536812001572 |
work_keys_str_mv | AT zhaominmin propane13diaminiumbistetrafluoroborate18crown612 |