Triphen­yl(prop-2-yn-1-yl)silane

In the title compound, C(21)H(18)Si, the coordination geometry around the Si atom is a slightly distorted tetra­hedron with C—Si—C angles in the range 106.05 (11) to 110.58 (10) ° and Si–C bond lengths in the range 1.855 (2) to 1.883 (3) Å. The alkyne C—C bond length is 1.167 (4) Å. The dihedral ang...

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Autores principales: Nelson, Björn, Schulte, Michaela, Strohmann, Carsten, Preut, Hans, Hiersemann, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275207/
https://www.ncbi.nlm.nih.gov/pubmed/22347063
http://dx.doi.org/10.1107/S1600536812001109
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author Nelson, Björn
Schulte, Michaela
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
author_facet Nelson, Björn
Schulte, Michaela
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
author_sort Nelson, Björn
collection PubMed
description In the title compound, C(21)H(18)Si, the coordination geometry around the Si atom is a slightly distorted tetra­hedron with C—Si—C angles in the range 106.05 (11) to 110.58 (10) ° and Si–C bond lengths in the range 1.855 (2) to 1.883 (3) Å. The alkyne C—C bond length is 1.167 (4) Å. The dihedral angles between the three phenyl rings are 63.89 (7), 86.38 (7) and 70.51 (8)°. In the crystal, mol­ecules inter­act only by van der Waals forces.
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spelling pubmed-32752072012-02-15 Triphen­yl(prop-2-yn-1-yl)silane Nelson, Björn Schulte, Michaela Strohmann, Carsten Preut, Hans Hiersemann, Martin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(18)Si, the coordination geometry around the Si atom is a slightly distorted tetra­hedron with C—Si—C angles in the range 106.05 (11) to 110.58 (10) ° and Si–C bond lengths in the range 1.855 (2) to 1.883 (3) Å. The alkyne C—C bond length is 1.167 (4) Å. The dihedral angles between the three phenyl rings are 63.89 (7), 86.38 (7) and 70.51 (8)°. In the crystal, mol­ecules inter­act only by van der Waals forces. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3275207/ /pubmed/22347063 http://dx.doi.org/10.1107/S1600536812001109 Text en © Nelson et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nelson, Björn
Schulte, Michaela
Strohmann, Carsten
Preut, Hans
Hiersemann, Martin
Triphen­yl(prop-2-yn-1-yl)silane
title Triphen­yl(prop-2-yn-1-yl)silane
title_full Triphen­yl(prop-2-yn-1-yl)silane
title_fullStr Triphen­yl(prop-2-yn-1-yl)silane
title_full_unstemmed Triphen­yl(prop-2-yn-1-yl)silane
title_short Triphen­yl(prop-2-yn-1-yl)silane
title_sort triphen­yl(prop-2-yn-1-yl)silane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275207/
https://www.ncbi.nlm.nih.gov/pubmed/22347063
http://dx.doi.org/10.1107/S1600536812001109
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AT strohmanncarsten triphenylprop2yn1ylsilane
AT preuthans triphenylprop2yn1ylsilane
AT hiersemannmartin triphenylprop2yn1ylsilane

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