N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide

In the title compound, C(14)H(12)N(2)O(5)S, the conformation between the N—H group and the ortho-nitro group in the sulfonyl benzene ring is syn and that between the C=O and meta-methyl groups in the benzoyl ring is anti. The mol­ecule is twisted at the S—N bond with a torsion angle of 64.3 (2)°. Th...

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Detalles Bibliográficos
Autores principales: Suchetan, P. A., Foro, Sabine, Gowda, B. Thimme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275215/
https://www.ncbi.nlm.nih.gov/pubmed/22347071
http://dx.doi.org/10.1107/S160053681200164X
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author Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
author_facet Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
author_sort Suchetan, P. A.
collection PubMed
description In the title compound, C(14)H(12)N(2)O(5)S, the conformation between the N—H group and the ortho-nitro group in the sulfonyl benzene ring is syn and that between the C=O and meta-methyl groups in the benzoyl ring is anti. The mol­ecule is twisted at the S—N bond with a torsion angle of 64.3 (2)°. The dihedral angle between the sulfonyl benzene ring and the —SO(2)—NH—C—O segment is 75.73 (7)° and that between the sulfonyl and benzoyl benzene rings is 89.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O(S) hydrogen bonds.
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spelling pubmed-32752152012-02-15 N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide Suchetan, P. A. Foro, Sabine Gowda, B. Thimme Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(12)N(2)O(5)S, the conformation between the N—H group and the ortho-nitro group in the sulfonyl benzene ring is syn and that between the C=O and meta-methyl groups in the benzoyl ring is anti. The mol­ecule is twisted at the S—N bond with a torsion angle of 64.3 (2)°. The dihedral angle between the sulfonyl benzene ring and the —SO(2)—NH—C—O segment is 75.73 (7)° and that between the sulfonyl and benzoyl benzene rings is 89.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N—H⋯O(S) hydrogen bonds. International Union of Crystallography 2012-01-18 /pmc/articles/PMC3275215/ /pubmed/22347071 http://dx.doi.org/10.1107/S160053681200164X Text en © Suchetan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suchetan, P. A.
Foro, Sabine
Gowda, B. Thimme
N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide
title N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide
title_full N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide
title_fullStr N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide
title_full_unstemmed N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide
title_short N-(3-Methyl­benzo­yl)-2-nitro­benzene­sulfonamide
title_sort n-(3-methyl­benzo­yl)-2-nitro­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275215/
https://www.ncbi.nlm.nih.gov/pubmed/22347071
http://dx.doi.org/10.1107/S160053681200164X
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AT forosabine n3methylbenzoyl2nitrobenzenesulfonamide
AT gowdabthimme n3methylbenzoyl2nitrobenzenesulfonamide

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