Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate

In the title compound, C(14)H(16)N(6)O(6)·C(2)H(6)O·H(2)O, both substit­uents of the benzene ring are approximately planar with maximum deviations from the mean plane of 0.0561 (12) (an imine N atom) and 0.1419 (11) Å (a meth­oxy O atom). The substituents are tilted out of the plane of the benzene r...

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Autores principales: Ismatov, Dilmurot, Azizov, Umarkhon, Ashurov, Jamshid, Talipov, Samat
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275217/
https://www.ncbi.nlm.nih.gov/pubmed/22347073
http://dx.doi.org/10.1107/S1600536812001237
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author Ismatov, Dilmurot
Azizov, Umarkhon
Ashurov, Jamshid
Talipov, Samat
author_facet Ismatov, Dilmurot
Azizov, Umarkhon
Ashurov, Jamshid
Talipov, Samat
author_sort Ismatov, Dilmurot
collection PubMed
description In the title compound, C(14)H(16)N(6)O(6)·C(2)H(6)O·H(2)O, both substit­uents of the benzene ring are approximately planar with maximum deviations from the mean plane of 0.0561 (12) (an imine N atom) and 0.1419 (11) Å (a meth­oxy O atom). The substituents are tilted out of the plane of the benzene ring by 64.48 (4) and 70.08 (5)°, respectively. In the crystal, mol­ecules form centrosymmetric dimers associated via pairs of N—H⋯O hydrogen bonds. The dimers are linked via the water and ethanol mol­ecules, forming two-dimensional hydrogen-bond networks lying parallel to (100).
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spelling pubmed-32752172012-02-15 Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate Ismatov, Dilmurot Azizov, Umarkhon Ashurov, Jamshid Talipov, Samat Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(16)N(6)O(6)·C(2)H(6)O·H(2)O, both substit­uents of the benzene ring are approximately planar with maximum deviations from the mean plane of 0.0561 (12) (an imine N atom) and 0.1419 (11) Å (a meth­oxy O atom). The substituents are tilted out of the plane of the benzene ring by 64.48 (4) and 70.08 (5)°, respectively. In the crystal, mol­ecules form centrosymmetric dimers associated via pairs of N—H⋯O hydrogen bonds. The dimers are linked via the water and ethanol mol­ecules, forming two-dimensional hydrogen-bond networks lying parallel to (100). International Union of Crystallography 2012-01-21 /pmc/articles/PMC3275217/ /pubmed/22347073 http://dx.doi.org/10.1107/S1600536812001237 Text en © Ismatov et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ismatov, Dilmurot
Azizov, Umarkhon
Ashurov, Jamshid
Talipov, Samat
Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
title Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
title_full Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
title_fullStr Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
title_full_unstemmed Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
title_short Methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
title_sort methyl 2-[(carbamoyl­amino)­imino]-2-(3-{1-[(carbamoyl­amino)­imino]-2-meth­oxy-2-oxoeth­yl}phen­yl)acetate ethanol monosolvate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275217/
https://www.ncbi.nlm.nih.gov/pubmed/22347073
http://dx.doi.org/10.1107/S1600536812001237
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AT ashurovjamshid methyl2carbamoylaminoimino231carbamoylaminoimino2methoxy2oxoethylphenylacetateethanolmonosolvatemonohydrate
AT talipovsamat methyl2carbamoylaminoimino231carbamoylaminoimino2methoxy2oxoethylphenylacetateethanolmonosolvatemonohydrate

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