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1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene
In the title compound, C(21)H(18)O(5)S(2), the two sulfur-bound phenyl rings lie on opposite sides of the methoxyphenyl group, making dihedral angles of 77.58 (8) and 87.45 (8)°with it. The dihedral angle between the sulfur-bound phenyl rings is 57.31 (8)°. In the crystal, π–π stacking is observed...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275222/ https://www.ncbi.nlm.nih.gov/pubmed/22347078 http://dx.doi.org/10.1107/S1600536812001961 |
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author | Asahara, Haruyasu Mayer, Peter Mayr, Herbert |
author_facet | Asahara, Haruyasu Mayer, Peter Mayr, Herbert |
author_sort | Asahara, Haruyasu |
collection | PubMed |
description | In the title compound, C(21)H(18)O(5)S(2), the two sulfur-bound phenyl rings lie on opposite sides of the methoxyphenyl group, making dihedral angles of 77.58 (8) and 87.45 (8)°with it. The dihedral angle between the sulfur-bound phenyl rings is 57.31 (8)°. In the crystal, π–π stacking is observed between the two sulfur-bound phenyl rings, with a centroid–centroid distance of 3.878 (1) Å and a dihedral angle of 7.58 (8)°. The molecules are linked by weak C—H⋯O and C—H⋯π contacts. |
format | Online Article Text |
id | pubmed-3275222 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32752222012-02-15 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene Asahara, Haruyasu Mayer, Peter Mayr, Herbert Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(18)O(5)S(2), the two sulfur-bound phenyl rings lie on opposite sides of the methoxyphenyl group, making dihedral angles of 77.58 (8) and 87.45 (8)°with it. The dihedral angle between the sulfur-bound phenyl rings is 57.31 (8)°. In the crystal, π–π stacking is observed between the two sulfur-bound phenyl rings, with a centroid–centroid distance of 3.878 (1) Å and a dihedral angle of 7.58 (8)°. The molecules are linked by weak C—H⋯O and C—H⋯π contacts. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3275222/ /pubmed/22347078 http://dx.doi.org/10.1107/S1600536812001961 Text en © Asahara et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Asahara, Haruyasu Mayer, Peter Mayr, Herbert 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
title | 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
title_full | 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
title_fullStr | 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
title_full_unstemmed | 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
title_short | 1-[2,2-Bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
title_sort | 1-[2,2-bis(phenylsulfonyl)ethenyl]-4-methoxybenzene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275222/ https://www.ncbi.nlm.nih.gov/pubmed/22347078 http://dx.doi.org/10.1107/S1600536812001961 |
work_keys_str_mv | AT asaharaharuyasu 122bisphenylsulfonylethenyl4methoxybenzene AT mayerpeter 122bisphenylsulfonylethenyl4methoxybenzene AT mayrherbert 122bisphenylsulfonylethenyl4methoxybenzene |