(E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile

In the title compound, C(18)H(16)N(2)O(2), the dihedral angle between the mean planes through the two benzene rings is 56.8 (6)°. The enoate group assumes an extended conformation. The hy­droxy­ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane...

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Detalles Bibliográficos
Autores principales: Govindan, E., Srinivasan, J., Bakthadoss, M., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275232/
https://www.ncbi.nlm.nih.gov/pubmed/22347088
http://dx.doi.org/10.1107/S1600536812001481
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author Govindan, E.
Srinivasan, J.
Bakthadoss, M.
SubbiahPandi, A.
author_facet Govindan, E.
Srinivasan, J.
Bakthadoss, M.
SubbiahPandi, A.
author_sort Govindan, E.
collection PubMed
description In the title compound, C(18)H(16)N(2)O(2), the dihedral angle between the mean planes through the two benzene rings is 56.8 (6)°. The enoate group assumes an extended conformation. The hy­droxy­ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.047 (1) Å for the hy­droxy­imino O atom. In the crystal, the mol­ecules are linked into cyclic centrosymmetric dimers with R (2) (2)(6) motifs via O—H⋯N hydrogen bonds.
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spelling pubmed-32752322012-02-15 (E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile Govindan, E. Srinivasan, J. Bakthadoss, M. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)N(2)O(2), the dihedral angle between the mean planes through the two benzene rings is 56.8 (6)°. The enoate group assumes an extended conformation. The hy­droxy­ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.047 (1) Å for the hy­droxy­imino O atom. In the crystal, the mol­ecules are linked into cyclic centrosymmetric dimers with R (2) (2)(6) motifs via O—H⋯N hydrogen bonds. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3275232/ /pubmed/22347088 http://dx.doi.org/10.1107/S1600536812001481 Text en © Govindan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Govindan, E.
Srinivasan, J.
Bakthadoss, M.
SubbiahPandi, A.
(E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
title (E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
title_full (E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
title_fullStr (E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
title_full_unstemmed (E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
title_short (E)-2-({2-[(E)-(Hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
title_sort (e)-2-({2-[(e)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-o-tolyl­acrylonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275232/
https://www.ncbi.nlm.nih.gov/pubmed/22347088
http://dx.doi.org/10.1107/S1600536812001481
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AT subbiahpandia e22ehydroxyiminomethylphenoxymethyl3otolylacrylonitrile

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