3-(3-Cyano­benz­yl)-1-methyl-1H-imidazol-3-ium hexa­fluoro­phosphate

In the title compound, C(12)H(12)N(3) (+)·PF(6) (−), the hexa­fluoro­phosphate anion is disordered over two orientations with refined site occupancies of 0.8071 (17) and 0.1929 (17). The dihedral angle between the imidazole and benzene rings in the cation is 71.26 (7)°. In the crystal, the cations a...

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Detalles Bibliográficos
Autores principales: Haque, Rosenani A., Zetty, Zulikha H., Salman, Abbas Washeel, Fun, Hoong-Kun, Ooi, Chin Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275236/
https://www.ncbi.nlm.nih.gov/pubmed/22347092
http://dx.doi.org/10.1107/S1600536812001882
Descripción
Sumario:In the title compound, C(12)H(12)N(3) (+)·PF(6) (−), the hexa­fluoro­phosphate anion is disordered over two orientations with refined site occupancies of 0.8071 (17) and 0.1929 (17). The dihedral angle between the imidazole and benzene rings in the cation is 71.26 (7)°. In the crystal, the cations and anions are linked by C—H⋯F and C—H⋯N hydrogen bonds into a three-dimensional network.

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