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2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione

The asymmetric unit of the title compound, C(19)H(11)F(3)N(2)O(2), contains two crystallographically unique mol­ecules which differ in the rotation of a phenyl ring and a –CF(3) substituent. The dihedral angles involving the pyrrole ring and the attached phenyl ring are 62.82 (8) and 71.54 (7)° in t...

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Autores principales: Roberts, Sue A., Martinez-Ariza, Guillermo, Dietrich, Justin, Hulme, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275242/
https://www.ncbi.nlm.nih.gov/pubmed/22347098
http://dx.doi.org/10.1107/S1600536812001675
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author Roberts, Sue A.
Martinez-Ariza, Guillermo
Dietrich, Justin
Hulme, Christopher
author_facet Roberts, Sue A.
Martinez-Ariza, Guillermo
Dietrich, Justin
Hulme, Christopher
author_sort Roberts, Sue A.
collection PubMed
description The asymmetric unit of the title compound, C(19)H(11)F(3)N(2)O(2), contains two crystallographically unique mol­ecules which differ in the rotation of a phenyl ring and a –CF(3) substituent. The dihedral angles involving the pyrrole ring and the attached phenyl ring are 62.82 (8) and 71.54 (7)° in the two molecules. The difference in the rotation of the CF(3) groups with respect to the pyrrolo rings to which they are attached is 23.5(1)°. For one mol­ecule, there is a close contact between an H atom and the centroid of the phenyl ring of an adjacent mol­ecule (2.572 Å). A similar contact is lacking in the second mol­ecule. In the crystal, N—H⋯O inter­actions connect adjacent mol­ecules into a chain normal to (01[Image: see text]). Crystallographically unique mol­ecules alternate along the hydrogen-bonded chains.
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spelling pubmed-32752422012-02-15 2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione Roberts, Sue A. Martinez-Ariza, Guillermo Dietrich, Justin Hulme, Christopher Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(11)F(3)N(2)O(2), contains two crystallographically unique mol­ecules which differ in the rotation of a phenyl ring and a –CF(3) substituent. The dihedral angles involving the pyrrole ring and the attached phenyl ring are 62.82 (8) and 71.54 (7)° in the two molecules. The difference in the rotation of the CF(3) groups with respect to the pyrrolo rings to which they are attached is 23.5(1)°. For one mol­ecule, there is a close contact between an H atom and the centroid of the phenyl ring of an adjacent mol­ecule (2.572 Å). A similar contact is lacking in the second mol­ecule. In the crystal, N—H⋯O inter­actions connect adjacent mol­ecules into a chain normal to (01[Image: see text]). Crystallographically unique mol­ecules alternate along the hydrogen-bonded chains. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3275242/ /pubmed/22347098 http://dx.doi.org/10.1107/S1600536812001675 Text en © Roberts et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Roberts, Sue A.
Martinez-Ariza, Guillermo
Dietrich, Justin
Hulme, Christopher
2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione
title 2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione
title_full 2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione
title_fullStr 2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione
title_full_unstemmed 2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione
title_short 2,4-Diphenyl-6-trifluoro­methyl-2,3-dihydro-1H,5H-pyrrolo­[3,4-c]pyrrole-1,3-dione
title_sort 2,4-diphenyl-6-trifluoro­methyl-2,3-dihydro-1h,5h-pyrrolo­[3,4-c]pyrrole-1,3-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275242/
https://www.ncbi.nlm.nih.gov/pubmed/22347098
http://dx.doi.org/10.1107/S1600536812001675
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