2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)

The title compound, C(18)H(20)Br(2)N(2)O(2), the heterocyclic ring adopts a chair conformation. The benzene rings make dihedral angles of 86.84 (10) and 60.73 (10)° with the mean plane of the heterocyclic ring. The dihedral angle between the two benzene rings is 79.77 (10)°. The mol­ecular structure...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Trujillo, Ginna Paola, Ríos-Motta, Jaime, Fejfarová, Karla, Dušek, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275243/
https://www.ncbi.nlm.nih.gov/pubmed/22347099
http://dx.doi.org/10.1107/S1600536812001985
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author Rivera, Augusto
Trujillo, Ginna Paola
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
author_facet Rivera, Augusto
Trujillo, Ginna Paola
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
author_sort Rivera, Augusto
collection PubMed
description The title compound, C(18)H(20)Br(2)N(2)O(2), the heterocyclic ring adopts a chair conformation. The benzene rings make dihedral angles of 86.84 (10) and 60.73 (10)° with the mean plane of the heterocyclic ring. The dihedral angle between the two benzene rings is 79.77 (10)°. The mol­ecular structure is stabilized by two intra­molecular hydrogen bonds between the phenolic hy­droxy groups and N atoms with graph-set motif S(6). The crystal structure is stabilized by weak C—H⋯π inter­actions.
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spelling pubmed-32752432012-02-15 2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol) Rivera, Augusto Trujillo, Ginna Paola Ríos-Motta, Jaime Fejfarová, Karla Dušek, Michal Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(20)Br(2)N(2)O(2), the heterocyclic ring adopts a chair conformation. The benzene rings make dihedral angles of 86.84 (10) and 60.73 (10)° with the mean plane of the heterocyclic ring. The dihedral angle between the two benzene rings is 79.77 (10)°. The mol­ecular structure is stabilized by two intra­molecular hydrogen bonds between the phenolic hy­droxy groups and N atoms with graph-set motif S(6). The crystal structure is stabilized by weak C—H⋯π inter­actions. International Union of Crystallography 2012-01-21 /pmc/articles/PMC3275243/ /pubmed/22347099 http://dx.doi.org/10.1107/S1600536812001985 Text en © Rivera et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rivera, Augusto
Trujillo, Ginna Paola
Ríos-Motta, Jaime
Fejfarová, Karla
Dušek, Michal
2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
title 2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
title_full 2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
title_fullStr 2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
title_full_unstemmed 2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
title_short 2,2′-[1,3-Diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
title_sort 2,2′-[1,3-diazinane-1,3-diylbis(methyl­ene)]bis­(4-bromo­phenol)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275243/
https://www.ncbi.nlm.nih.gov/pubmed/22347099
http://dx.doi.org/10.1107/S1600536812001985
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