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ent-(15S)-Pimar-8(14)-ene-15,16-diol
The title compound {systematic name: (S)-1-[(2S,4aR,8aR)-2,4b,8,8-tetramethyl-2,3,4,4a,4b,5,6,7,8,8a,9,10-dodecahydrophenanthren-2-yl]ethane-1,2-diol}, C(20)H(34)O(2), is an ent-pimarane diterpenoid which was isolated from the stem bark of Ceriops tagal. In the asymmetric unit, there are two crys...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275262/ https://www.ncbi.nlm.nih.gov/pubmed/22347118 http://dx.doi.org/10.1107/S1600536812002565 |
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author | Fun, Hoong-Kun Chantrapromma, Suchada Pakhathirathien, Charoen Karalai, Chatchanok Chantrapromma, Kan |
author_facet | Fun, Hoong-Kun Chantrapromma, Suchada Pakhathirathien, Charoen Karalai, Chatchanok Chantrapromma, Kan |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The title compound {systematic name: (S)-1-[(2S,4aR,8aR)-2,4b,8,8-tetramethyl-2,3,4,4a,4b,5,6,7,8,8a,9,10-dodecahydrophenanthren-2-yl]ethane-1,2-diol}, C(20)H(34)O(2), is an ent-pimarane diterpenoid which was isolated from the stem bark of Ceriops tagal. In the asymmetric unit, there are two crystallographically independent molecules, which are conformationally almost identical. In each molecule, the two cyclohexane rings of the fused three-ring system adopt chair conformations, while the cyclohexene ring is in an envelope conformation, with the methylene C atom next to the side chain as the flap atom. In the crystal, molecules are stacked in columns along the b axis through O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3275262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32752622012-02-15 ent-(15S)-Pimar-8(14)-ene-15,16-diol Fun, Hoong-Kun Chantrapromma, Suchada Pakhathirathien, Charoen Karalai, Chatchanok Chantrapromma, Kan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound {systematic name: (S)-1-[(2S,4aR,8aR)-2,4b,8,8-tetramethyl-2,3,4,4a,4b,5,6,7,8,8a,9,10-dodecahydrophenanthren-2-yl]ethane-1,2-diol}, C(20)H(34)O(2), is an ent-pimarane diterpenoid which was isolated from the stem bark of Ceriops tagal. In the asymmetric unit, there are two crystallographically independent molecules, which are conformationally almost identical. In each molecule, the two cyclohexane rings of the fused three-ring system adopt chair conformations, while the cyclohexene ring is in an envelope conformation, with the methylene C atom next to the side chain as the flap atom. In the crystal, molecules are stacked in columns along the b axis through O—H⋯O hydrogen bonds. International Union of Crystallography 2012-01-25 /pmc/articles/PMC3275262/ /pubmed/22347118 http://dx.doi.org/10.1107/S1600536812002565 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chantrapromma, Suchada Pakhathirathien, Charoen Karalai, Chatchanok Chantrapromma, Kan ent-(15S)-Pimar-8(14)-ene-15,16-diol |
title |
ent-(15S)-Pimar-8(14)-ene-15,16-diol |
title_full |
ent-(15S)-Pimar-8(14)-ene-15,16-diol |
title_fullStr |
ent-(15S)-Pimar-8(14)-ene-15,16-diol |
title_full_unstemmed |
ent-(15S)-Pimar-8(14)-ene-15,16-diol |
title_short |
ent-(15S)-Pimar-8(14)-ene-15,16-diol |
title_sort | ent-(15s)-pimar-8(14)-ene-15,16-diol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275262/ https://www.ncbi.nlm.nih.gov/pubmed/22347118 http://dx.doi.org/10.1107/S1600536812002565 |
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