2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime

The piperidin-4-one ring in the title compound, C(26)H(26)Cl(2)N(2)O, exists in a chair conformation with equatorial orientations of the methyl and 4-chlorophenyl groups. The C atom bonded to the oxime group is statistically planar (bond-angle sum = 360.0°) although the C—C=N bond angles are very di...

Descripción completa

Detalles Bibliográficos
Autores principales: Park, Dong Ho, Ramkumar, V., Parthiban, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275266/
https://www.ncbi.nlm.nih.gov/pubmed/22347122
http://dx.doi.org/10.1107/S1600536812002152
_version_ 1782223199264571392
author Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_facet Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_sort Park, Dong Ho
collection PubMed
description The piperidin-4-one ring in the title compound, C(26)H(26)Cl(2)N(2)O, exists in a chair conformation with equatorial orientations of the methyl and 4-chlorophenyl groups. The C atom bonded to the oxime group is statistically planar (bond-angle sum = 360.0°) although the C—C=N bond angles are very different [117.83 (15) and 127.59 (15)°]. The dihedral angle between the chloro­phenyl rings is 54.75 (4)°. In the crystal, mol­ecules inter­act via van der Waals forces.
format Online
Article
Text
id pubmed-3275266
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32752662012-02-15 2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime Park, Dong Ho Ramkumar, V. Parthiban, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The piperidin-4-one ring in the title compound, C(26)H(26)Cl(2)N(2)O, exists in a chair conformation with equatorial orientations of the methyl and 4-chlorophenyl groups. The C atom bonded to the oxime group is statistically planar (bond-angle sum = 360.0°) although the C—C=N bond angles are very different [117.83 (15) and 127.59 (15)°]. The dihedral angle between the chloro­phenyl rings is 54.75 (4)°. In the crystal, mol­ecules inter­act via van der Waals forces. International Union of Crystallography 2012-01-25 /pmc/articles/PMC3275266/ /pubmed/22347122 http://dx.doi.org/10.1107/S1600536812002152 Text en © Park et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Park, Dong Ho
Ramkumar, V.
Parthiban, P.
2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime
title 2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime
title_full 2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime
title_fullStr 2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime
title_full_unstemmed 2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime
title_short 2,6-Bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one O-benzyl­oxime
title_sort 2,6-bis(4-chloro­phen­yl)-1,3-dimethyl­piperidin-4-one o-benzyl­oxime
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275266/
https://www.ncbi.nlm.nih.gov/pubmed/22347122
http://dx.doi.org/10.1107/S1600536812002152
work_keys_str_mv AT parkdongho 26bis4chlorophenyl13dimethylpiperidin4oneobenzyloxime
AT ramkumarv 26bis4chlorophenyl13dimethylpiperidin4oneobenzyloxime
AT parthibanp 26bis4chlorophenyl13dimethylpiperidin4oneobenzyloxime

Ejemplares similares