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1-[(4-Bromophenyl)(morpholin-4-yl)methyl]naphthalen-2-ol
The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromobenzaldehyde, 2-naphthol and morpholine. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring syste...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275269/ https://www.ncbi.nlm.nih.gov/pubmed/22347125 http://dx.doi.org/10.1107/S1600536812002620 |
Sumario: | The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromobenzaldehyde, 2-naphthol and morpholine. The molecular conformation is stabilized by an intramolecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring system and the benzene ring is 76.72 (8)°. In addition to the intramolecular hydrogen bond, the O—H groups of centrosymmetrically related molecules form short intermolecular H⋯O contacts of 2.59 Å. These molecules are also linked by pairs of C—H⋯O interactions, generating an R (2) (2)(14) motif. |
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