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1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol

The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring syste...

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Detalles Bibliográficos
Autor principal: Zhao, Qun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275269/
https://www.ncbi.nlm.nih.gov/pubmed/22347125
http://dx.doi.org/10.1107/S1600536812002620
Descripción
Sumario:The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring system and the benzene ring is 76.72 (8)°. In addition to the intra­molecular hydrogen bond, the O—H groups of centrosymmetrically related mol­ecules form short inter­molecular H⋯O contacts of 2.59 Å. These mol­ecules are also linked by pairs of C—H⋯O inter­actions, generating an R (2) (2)(14) motif.