1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol

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The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring syste...

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Detalles Bibliográficos
Autor principal: Zhao, Qun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275269/
https://www.ncbi.nlm.nih.gov/pubmed/22347125
http://dx.doi.org/10.1107/S1600536812002620
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author Zhao, Qun
author_facet Zhao, Qun
author_sort Zhao, Qun
collection PubMed
description The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring system and the benzene ring is 76.72 (8)°. In addition to the intra­molecular hydrogen bond, the O—H groups of centrosymmetrically related mol­ecules form short inter­molecular H⋯O contacts of 2.59 Å. These mol­ecules are also linked by pairs of C—H⋯O inter­actions, generating an R (2) (2)(14) motif.
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spelling pubmed-32752692012-02-15 1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol Zhao, Qun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(20)BrNO(2), was obtained from a condensation reaction of 4-bromo­benzaldehyde, 2-naphthol and morpholine. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯N hydrogen bond, closing a six-membered ring. The dihedral angle between the naphthalene ring system and the benzene ring is 76.72 (8)°. In addition to the intra­molecular hydrogen bond, the O—H groups of centrosymmetrically related mol­ecules form short inter­molecular H⋯O contacts of 2.59 Å. These mol­ecules are also linked by pairs of C—H⋯O inter­actions, generating an R (2) (2)(14) motif. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3275269/ /pubmed/22347125 http://dx.doi.org/10.1107/S1600536812002620 Text en © Qun Zhao 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Qun
1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
title 1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
title_full 1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
title_fullStr 1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
title_full_unstemmed 1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
title_short 1-[(4-Bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
title_sort 1-[(4-bromo­phen­yl)(morpholin-4-yl)meth­yl]naphthalen-2-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275269/
https://www.ncbi.nlm.nih.gov/pubmed/22347125
http://dx.doi.org/10.1107/S1600536812002620
work_keys_str_mv AT zhaoqun 14bromophenylmorpholin4ylmethylnaphthalen2ol

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