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3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran
In the title compound, C(18)H(17)ClO(2)S, the 3-chlorophenyl ring makes a dihedral angle of 72.62 (4)° with the mean plane of the benzofuran fragment. In the crystal, molecules are linked by weak intermolecular C—H⋯O and C—H⋯π interactions. The crystal structure also exhibits a slipped π–π inter...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275274/ https://www.ncbi.nlm.nih.gov/pubmed/22347130 http://dx.doi.org/10.1107/S1600536812002887 |
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author | Choi, Hong Dae Seo, Pil Ja Lee, Uk |
author_facet | Choi, Hong Dae Seo, Pil Ja Lee, Uk |
author_sort | Choi, Hong Dae |
collection | PubMed |
description | In the title compound, C(18)H(17)ClO(2)S, the 3-chlorophenyl ring makes a dihedral angle of 72.62 (4)° with the mean plane of the benzofuran fragment. In the crystal, molecules are linked by weak intermolecular C—H⋯O and C—H⋯π interactions. The crystal structure also exhibits a slipped π–π interaction between the 3-chlorophenyl rings of adjacent molecules [centroid–centroid distance = 3.751 (2) Å, interplanar distance = 3.450 (2) Å and slippage = 1.472 (2) Å]. |
format | Online Article Text |
id | pubmed-3275274 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32752742012-02-15 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran Choi, Hong Dae Seo, Pil Ja Lee, Uk Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)ClO(2)S, the 3-chlorophenyl ring makes a dihedral angle of 72.62 (4)° with the mean plane of the benzofuran fragment. In the crystal, molecules are linked by weak intermolecular C—H⋯O and C—H⋯π interactions. The crystal structure also exhibits a slipped π–π interaction between the 3-chlorophenyl rings of adjacent molecules [centroid–centroid distance = 3.751 (2) Å, interplanar distance = 3.450 (2) Å and slippage = 1.472 (2) Å]. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3275274/ /pubmed/22347130 http://dx.doi.org/10.1107/S1600536812002887 Text en © Choi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Choi, Hong Dae Seo, Pil Ja Lee, Uk 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
title | 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
title_full | 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
title_fullStr | 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
title_full_unstemmed | 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
title_short | 3-(3-Chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
title_sort | 3-(3-chlorophenylsulfinyl)-2,4,6,7-tetramethyl-1-benzofuran |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275274/ https://www.ncbi.nlm.nih.gov/pubmed/22347130 http://dx.doi.org/10.1107/S1600536812002887 |
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