1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol

In the title compound, C(17)H(13)BrClNO, the dihedral angle between the naphthol ring system and the chloro­benzene ring is 76.59 (11)°. This twisted conformation is supported by an intra­molecular O—H⋯N hydrogen bond. In the crystal, [100] chains arise, with adjacent mol­ecules linked by an N—H⋯O h...

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Detalles Bibliográficos
Autores principales: Praveen, A. S., Yathirajan, H. S., Harrison, William T. A., Slawin, Alexandra M. Z.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275275/
https://www.ncbi.nlm.nih.gov/pubmed/22347131
http://dx.doi.org/10.1107/S1600536812002905
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author Praveen, A. S.
Yathirajan, H. S.
Harrison, William T. A.
Slawin, Alexandra M. Z.
author_facet Praveen, A. S.
Yathirajan, H. S.
Harrison, William T. A.
Slawin, Alexandra M. Z.
author_sort Praveen, A. S.
collection PubMed
description In the title compound, C(17)H(13)BrClNO, the dihedral angle between the naphthol ring system and the chloro­benzene ring is 76.59 (11)°. This twisted conformation is supported by an intra­molecular O—H⋯N hydrogen bond. In the crystal, [100] chains arise, with adjacent mol­ecules linked by an N—H⋯O hydrogen bond, a C—H⋯π inter­action and an aromatic π–π stacking contact [centroid-to-centroid separation = 3.783 (2) Å]. Weak C—H⋯O inter­actions also occur.
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spelling pubmed-32752752012-02-15 1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol Praveen, A. S. Yathirajan, H. S. Harrison, William T. A. Slawin, Alexandra M. Z. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(13)BrClNO, the dihedral angle between the naphthol ring system and the chloro­benzene ring is 76.59 (11)°. This twisted conformation is supported by an intra­molecular O—H⋯N hydrogen bond. In the crystal, [100] chains arise, with adjacent mol­ecules linked by an N—H⋯O hydrogen bond, a C—H⋯π inter­action and an aromatic π–π stacking contact [centroid-to-centroid separation = 3.783 (2) Å]. Weak C—H⋯O inter­actions also occur. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3275275/ /pubmed/22347131 http://dx.doi.org/10.1107/S1600536812002905 Text en © Praveen et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Praveen, A. S.
Yathirajan, H. S.
Harrison, William T. A.
Slawin, Alexandra M. Z.
1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
title 1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
title_full 1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
title_fullStr 1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
title_full_unstemmed 1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
title_short 1-[Amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
title_sort 1-[amino­(4-chloro­phen­yl)meth­yl]-6-bromo­naphthalen-2-ol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275275/
https://www.ncbi.nlm.nih.gov/pubmed/22347131
http://dx.doi.org/10.1107/S1600536812002905
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