Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate

The title compound, C(37)H(31)ClN(4)O(4), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The pyrrole rings in both mol­ecules are connected via cis fusion, whereas one ring has a twisted conformation and the other assumes a half-chair conformation. In the crystal, the A mol­ecule...

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Detalles Bibliográficos
Autores principales: Kamatchi, P., Jagadeesan, G., Pramesh, M., Perumal, P. T., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275287/
https://www.ncbi.nlm.nih.gov/pubmed/22347143
http://dx.doi.org/10.1107/S1600536812002450
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author Kamatchi, P.
Jagadeesan, G.
Pramesh, M.
Perumal, P. T.
Aravindhan, S.
author_facet Kamatchi, P.
Jagadeesan, G.
Pramesh, M.
Perumal, P. T.
Aravindhan, S.
author_sort Kamatchi, P.
collection PubMed
description The title compound, C(37)H(31)ClN(4)O(4), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The pyrrole rings in both mol­ecules are connected via cis fusion, whereas one ring has a twisted conformation and the other assumes a half-chair conformation. In the crystal, the A mol­ecules form inversion dimers via a pair of C—H⋯Cl inter­actions, while the B mol­ecules form chains propagating in [1[Image: see text]0], via C—H⋯O inter­actions. In the crystal, there are also a number of C—H⋯π inter­actions present.
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spelling pubmed-32752872012-02-15 Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate Kamatchi, P. Jagadeesan, G. Pramesh, M. Perumal, P. T. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(37)H(31)ClN(4)O(4), crystallizes with two mol­ecules (A and B) in the asymmetric unit. The pyrrole rings in both mol­ecules are connected via cis fusion, whereas one ring has a twisted conformation and the other assumes a half-chair conformation. In the crystal, the A mol­ecules form inversion dimers via a pair of C—H⋯Cl inter­actions, while the B mol­ecules form chains propagating in [1[Image: see text]0], via C—H⋯O inter­actions. In the crystal, there are also a number of C—H⋯π inter­actions present. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3275287/ /pubmed/22347143 http://dx.doi.org/10.1107/S1600536812002450 Text en © Kamatchi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kamatchi, P.
Jagadeesan, G.
Pramesh, M.
Perumal, P. T.
Aravindhan, S.
Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
title Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
title_full Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
title_fullStr Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
title_full_unstemmed Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
title_short Ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1H-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
title_sort ethyl 2-benzyl-3-[3-(4-chloro­phen­yl)-1-phenyl-1h-pyrazol-4-yl]-4,6-dioxo-5-phenyl­octa­hydro­pyrrolo­[3,4-c]pyrrole-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275287/
https://www.ncbi.nlm.nih.gov/pubmed/22347143
http://dx.doi.org/10.1107/S1600536812002450
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AT aravindhans ethyl2benzyl334chlorophenyl1phenyl1hpyrazol4yl46dioxo5phenyloctahydropyrrolo34cpyrrole1carboxylate

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