Trimeth­yl(triphenyl­meth­oxy)silane

In the title mol­ecule, C(22)H(24)OSi, the Si—O—C angle is 139.79 (11)°, the O—C—C angles of the triphenyl­meth­oxy group are in the range 106.13 (13)–109.22 (14)° and the O—Si—C angles of the trimethyl­sil­yloxy group are in the range 103.08 (10)–113.53 (10)°. In the crystal, face-to-face π–π inter...

Descripción completa

Detalles Bibliográficos
Autores principales: Anthal, Sumati, Banerjee, Bubun, Brahmacharia, Goutam, Kant, Rajni, Gupta, Vivek K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275290/
https://www.ncbi.nlm.nih.gov/pubmed/22347146
http://dx.doi.org/10.1107/S1600536812003170
_version_ 1782223204875501568
author Anthal, Sumati
Banerjee, Bubun
Brahmacharia, Goutam
Kant, Rajni
Gupta, Vivek K.
author_facet Anthal, Sumati
Banerjee, Bubun
Brahmacharia, Goutam
Kant, Rajni
Gupta, Vivek K.
author_sort Anthal, Sumati
collection PubMed
description In the title mol­ecule, C(22)H(24)OSi, the Si—O—C angle is 139.79 (11)°, the O—C—C angles of the triphenyl­meth­oxy group are in the range 106.13 (13)–109.22 (14)° and the O—Si—C angles of the trimethyl­sil­yloxy group are in the range 103.08 (10)–113.53 (10)°. In the crystal, face-to-face π–π interactions are observed between the phenyl rings [centroid separation = 4.194 (1) Å, interplanar spacing = 3.474 Å and centroid shift = 2.35 Å]. The three phenyl groups of the triphenyl­methyl substituent are mutually nearly perpendicular, with dihedral angles in the range 80.49 (8)–81.53 (8)°. There are only weak inter­molecular van der Waals inter­actions in the crystal.
format Online
Article
Text
id pubmed-3275290
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32752902012-02-15 Trimeth­yl(triphenyl­meth­oxy)silane Anthal, Sumati Banerjee, Bubun Brahmacharia, Goutam Kant, Rajni Gupta, Vivek K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(22)H(24)OSi, the Si—O—C angle is 139.79 (11)°, the O—C—C angles of the triphenyl­meth­oxy group are in the range 106.13 (13)–109.22 (14)° and the O—Si—C angles of the trimethyl­sil­yloxy group are in the range 103.08 (10)–113.53 (10)°. In the crystal, face-to-face π–π interactions are observed between the phenyl rings [centroid separation = 4.194 (1) Å, interplanar spacing = 3.474 Å and centroid shift = 2.35 Å]. The three phenyl groups of the triphenyl­methyl substituent are mutually nearly perpendicular, with dihedral angles in the range 80.49 (8)–81.53 (8)°. There are only weak inter­molecular van der Waals inter­actions in the crystal. International Union of Crystallography 2012-01-31 /pmc/articles/PMC3275290/ /pubmed/22347146 http://dx.doi.org/10.1107/S1600536812003170 Text en © Anthal et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Anthal, Sumati
Banerjee, Bubun
Brahmacharia, Goutam
Kant, Rajni
Gupta, Vivek K.
Trimeth­yl(triphenyl­meth­oxy)silane
title Trimeth­yl(triphenyl­meth­oxy)silane
title_full Trimeth­yl(triphenyl­meth­oxy)silane
title_fullStr Trimeth­yl(triphenyl­meth­oxy)silane
title_full_unstemmed Trimeth­yl(triphenyl­meth­oxy)silane
title_short Trimeth­yl(triphenyl­meth­oxy)silane
title_sort trimeth­yl(triphenyl­meth­oxy)silane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275290/
https://www.ncbi.nlm.nih.gov/pubmed/22347146
http://dx.doi.org/10.1107/S1600536812003170
work_keys_str_mv AT anthalsumati trimethyltriphenylmethoxysilane
AT banerjeebubun trimethyltriphenylmethoxysilane
AT brahmachariagoutam trimethyltriphenylmethoxysilane
AT kantrajni trimethyltriphenylmethoxysilane
AT guptavivekk trimethyltriphenylmethoxysilane

Ejemplares similares