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Lattice-patterned LC-polymer composites containing various nanoparticles as additives

In this study, we show the effect of various nanoparticle additives on phase separation behavior of a lattice-patterned liquid crystal [LC]-polymer composite system and on interfacial properties between the LC and polymer. Lattice-patterned LC-polymer composites were fabricated by exposing to UV lig...

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Autores principales: Sim, Kyoseung, Sung, Shi-Joon, Jung, Eun-Ae, Son, Dae-Ho, Kim, Dae-Hwan, Kang, Jin-Kyu, Cho, Kuk Young
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275447/
https://www.ncbi.nlm.nih.gov/pubmed/22222011
http://dx.doi.org/10.1186/1556-276X-7-46
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author Sim, Kyoseung
Sung, Shi-Joon
Jung, Eun-Ae
Son, Dae-Ho
Kim, Dae-Hwan
Kang, Jin-Kyu
Cho, Kuk Young
author_facet Sim, Kyoseung
Sung, Shi-Joon
Jung, Eun-Ae
Son, Dae-Ho
Kim, Dae-Hwan
Kang, Jin-Kyu
Cho, Kuk Young
author_sort Sim, Kyoseung
collection PubMed
description In this study, we show the effect of various nanoparticle additives on phase separation behavior of a lattice-patterned liquid crystal [LC]-polymer composite system and on interfacial properties between the LC and polymer. Lattice-patterned LC-polymer composites were fabricated by exposing to UV light a mixture of a prepolymer, an LC, and SiO(2 )nanoparticles positioned under a patterned photomask. This resulted in the formation of an LC and prepolymer region through phase separation. We found that the incorporation of SiO(2 )nanoparticles significantly affected the electro-optical properties of the lattice-patterned LC-polymer composites. This effect is a fundamental characteristic of flexible displays. The electro-optical properties depend on the size and surface functional groups of the SiO(2 )nanoparticles. Compared with untreated pristine SiO(2 )nanoparticles, which adversely affect the performance of LC molecules surrounded by polymer walls, SiO(2 )nanoparticles with surface functional groups were found to improve the electro-optical properties of the lattice-patterned LC-polymer composites by increasing the quantity of SiO(2 )nanoparticles. The surface functional groups of the SiO(2 )nanoparticles were closely related to the distribution of SiO(2 )nanoparticles in the LC-polymer composites, and they influenced the electro-optical properties of the LC molecules. It is clear from our work that the introduction of nanoparticles into a lattice-patterned LC-polymer composite provides a method for controlling and improving the composite's electro-optical properties. This technique can be used to produce flexible substrates for various flexible electronic devices.
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spelling pubmed-32754472012-02-09 Lattice-patterned LC-polymer composites containing various nanoparticles as additives Sim, Kyoseung Sung, Shi-Joon Jung, Eun-Ae Son, Dae-Ho Kim, Dae-Hwan Kang, Jin-Kyu Cho, Kuk Young Nanoscale Res Lett Nano Express In this study, we show the effect of various nanoparticle additives on phase separation behavior of a lattice-patterned liquid crystal [LC]-polymer composite system and on interfacial properties between the LC and polymer. Lattice-patterned LC-polymer composites were fabricated by exposing to UV light a mixture of a prepolymer, an LC, and SiO(2 )nanoparticles positioned under a patterned photomask. This resulted in the formation of an LC and prepolymer region through phase separation. We found that the incorporation of SiO(2 )nanoparticles significantly affected the electro-optical properties of the lattice-patterned LC-polymer composites. This effect is a fundamental characteristic of flexible displays. The electro-optical properties depend on the size and surface functional groups of the SiO(2 )nanoparticles. Compared with untreated pristine SiO(2 )nanoparticles, which adversely affect the performance of LC molecules surrounded by polymer walls, SiO(2 )nanoparticles with surface functional groups were found to improve the electro-optical properties of the lattice-patterned LC-polymer composites by increasing the quantity of SiO(2 )nanoparticles. The surface functional groups of the SiO(2 )nanoparticles were closely related to the distribution of SiO(2 )nanoparticles in the LC-polymer composites, and they influenced the electro-optical properties of the LC molecules. It is clear from our work that the introduction of nanoparticles into a lattice-patterned LC-polymer composite provides a method for controlling and improving the composite's electro-optical properties. This technique can be used to produce flexible substrates for various flexible electronic devices. Springer 2012-01-05 /pmc/articles/PMC3275447/ /pubmed/22222011 http://dx.doi.org/10.1186/1556-276X-7-46 Text en Copyright ©2012 Sim et al; licensee Springer. http://creativecommons.org/licenses/by/2.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Nano Express
Sim, Kyoseung
Sung, Shi-Joon
Jung, Eun-Ae
Son, Dae-Ho
Kim, Dae-Hwan
Kang, Jin-Kyu
Cho, Kuk Young
Lattice-patterned LC-polymer composites containing various nanoparticles as additives
title Lattice-patterned LC-polymer composites containing various nanoparticles as additives
title_full Lattice-patterned LC-polymer composites containing various nanoparticles as additives
title_fullStr Lattice-patterned LC-polymer composites containing various nanoparticles as additives
title_full_unstemmed Lattice-patterned LC-polymer composites containing various nanoparticles as additives
title_short Lattice-patterned LC-polymer composites containing various nanoparticles as additives
title_sort lattice-patterned lc-polymer composites containing various nanoparticles as additives
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3275447/
https://www.ncbi.nlm.nih.gov/pubmed/22222011
http://dx.doi.org/10.1186/1556-276X-7-46
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