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Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method

In order to study the chemical oscillatory behavior and mechanism of a new chlorine dioxide-iodide ion-methyl acetoacetate reaction system, a series of experiments were done by using UV-Vis and online FTIR spectrophotometric method. The initial concentrations of methyl acetoacetate, chlorine dioxide...

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Detalles Bibliográficos
Autores principales: Shi, Laishun, Wang, Xiaomei, Li, Na, Liu, Jie, Yan, Chunying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Scientific World Journal 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3289901/
https://www.ncbi.nlm.nih.gov/pubmed/22454614
http://dx.doi.org/10.1100/2012/918620
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author Shi, Laishun
Wang, Xiaomei
Li, Na
Liu, Jie
Yan, Chunying
author_facet Shi, Laishun
Wang, Xiaomei
Li, Na
Liu, Jie
Yan, Chunying
author_sort Shi, Laishun
collection PubMed
description In order to study the chemical oscillatory behavior and mechanism of a new chlorine dioxide-iodide ion-methyl acetoacetate reaction system, a series of experiments were done by using UV-Vis and online FTIR spectrophotometric method. The initial concentrations of methyl acetoacetate, chlorine dioxide, potassium iodide, and sulfuric acid and the pH value have great influence on the oscillation observed at wavelength of 289 nm. There is a preoscillatory or induction period, and the amplitude and the number of oscillations are associated with the initial concentration of reactants. The equations for the triiodide ion reaction rate changing with reaction time and the initial concentrations in the oscillation stage were obtained. Oscillation reaction can be accelerated by increasing temperature. The apparent activation energies in terms of the induction period and the oscillation period were 26.02 KJ/mol and 17.65 KJ/mol, respectively. The intermediates were detected by the online FTIR analysis. Based upon the experimental data in this work and in the literature, a plausible reaction mechanism was proposed for the oscillation reaction.
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spelling pubmed-32899012012-03-27 Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method Shi, Laishun Wang, Xiaomei Li, Na Liu, Jie Yan, Chunying ScientificWorldJournal Research Article In order to study the chemical oscillatory behavior and mechanism of a new chlorine dioxide-iodide ion-methyl acetoacetate reaction system, a series of experiments were done by using UV-Vis and online FTIR spectrophotometric method. The initial concentrations of methyl acetoacetate, chlorine dioxide, potassium iodide, and sulfuric acid and the pH value have great influence on the oscillation observed at wavelength of 289 nm. There is a preoscillatory or induction period, and the amplitude and the number of oscillations are associated with the initial concentration of reactants. The equations for the triiodide ion reaction rate changing with reaction time and the initial concentrations in the oscillation stage were obtained. Oscillation reaction can be accelerated by increasing temperature. The apparent activation energies in terms of the induction period and the oscillation period were 26.02 KJ/mol and 17.65 KJ/mol, respectively. The intermediates were detected by the online FTIR analysis. Based upon the experimental data in this work and in the literature, a plausible reaction mechanism was proposed for the oscillation reaction. The Scientific World Journal 2012-02-01 /pmc/articles/PMC3289901/ /pubmed/22454614 http://dx.doi.org/10.1100/2012/918620 Text en Copyright © 2012 Laishun Shi et al. https://creativecommons.org/licenses/by/3.0/ This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Shi, Laishun
Wang, Xiaomei
Li, Na
Liu, Jie
Yan, Chunying
Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method
title Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method
title_full Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method
title_fullStr Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method
title_full_unstemmed Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method
title_short Chlorine Dioxide-Iodide-Methyl Acetoacetate Oscillation Reaction Investigated by UV-Vis and Online FTIR Spectrophotometric Method
title_sort chlorine dioxide-iodide-methyl acetoacetate oscillation reaction investigated by uv-vis and online ftir spectrophotometric method
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3289901/
https://www.ncbi.nlm.nih.gov/pubmed/22454614
http://dx.doi.org/10.1100/2012/918620
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AT lina chlorinedioxideiodidemethylacetoacetateoscillationreactioninvestigatedbyuvvisandonlineftirspectrophotometricmethod
AT liujie chlorinedioxideiodidemethylacetoacetateoscillationreactioninvestigatedbyuvvisandonlineftirspectrophotometricmethod
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