1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene

In the title compound, C(15)H(15)N(5)O(4), a nitro­formazan derivative, the formazan unit is essentially planar with an r.m.s. deviation of 0.0204 (6) Å and adopts a closed syn,s-cis configuration with an intra­molecular N—H⋯N hydrogen bond. The formazan plane makes dihedral angles of 4.32 (5) and 2...

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Detalles Bibliográficos
Autores principales: von Eschwege, Karel G., Muller, Fabian, Hill, Tania N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295411/
https://www.ncbi.nlm.nih.gov/pubmed/22412522
http://dx.doi.org/10.1107/S1600536812004175
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author von Eschwege, Karel G.
Muller, Fabian
Hill, Tania N.
author_facet von Eschwege, Karel G.
Muller, Fabian
Hill, Tania N.
author_sort von Eschwege, Karel G.
collection PubMed
description In the title compound, C(15)H(15)N(5)O(4), a nitro­formazan derivative, the formazan unit is essentially planar with an r.m.s. deviation of 0.0204 (6) Å and adopts a closed syn,s-cis configuration with an intra­molecular N—H⋯N hydrogen bond. The formazan plane makes dihedral angles of 4.32 (5) and 24.35 (5)° with the benzene rings. The dihedral angle between the formazan plane and the nitro group is 12.58 (8)°. In the crystal, C—H⋯O inter­actions connect the mol­ecules into an inversion dimer.
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spelling pubmed-32954112012-03-12 1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene von Eschwege, Karel G. Muller, Fabian Hill, Tania N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)N(5)O(4), a nitro­formazan derivative, the formazan unit is essentially planar with an r.m.s. deviation of 0.0204 (6) Å and adopts a closed syn,s-cis configuration with an intra­molecular N—H⋯N hydrogen bond. The formazan plane makes dihedral angles of 4.32 (5) and 24.35 (5)° with the benzene rings. The dihedral angle between the formazan plane and the nitro group is 12.58 (8)°. In the crystal, C—H⋯O inter­actions connect the mol­ecules into an inversion dimer. International Union of Crystallography 2012-02-04 /pmc/articles/PMC3295411/ /pubmed/22412522 http://dx.doi.org/10.1107/S1600536812004175 Text en © Eschwege et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
von Eschwege, Karel G.
Muller, Fabian
Hill, Tania N.
1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
title 1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
title_full 1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
title_fullStr 1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
title_full_unstemmed 1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
title_short 1-(2-Meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
title_sort 1-(2-meth­oxy­phen­yl)-2-{[2-(2-meth­oxy­phen­yl)hydrazinyl­idene](nitro)­meth­yl}diazene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295411/
https://www.ncbi.nlm.nih.gov/pubmed/22412522
http://dx.doi.org/10.1107/S1600536812004175
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AT mullerfabian 12methoxyphenyl222methoxyphenylhydrazinylidenenitromethyldiazene
AT hilltanian 12methoxyphenyl222methoxyphenylhydrazinylidenenitromethyldiazene

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