1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside

The title compound, C(19)H(19)NO(10), was obtained from the reaction of α-d-1-bromo-2,3,4-tri-O-acetylxylose with N-hy­droxy­phthalimide in the presence of potassium carbonate. The asymmetric unit contains two independent mol­ecules, in which the O—CH—O—N torsion angles are 73.0 (4) and 65.0 (4)°. T...

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Detalles Bibliográficos
Autores principales: Tian, Runan, Haoriqinbatu, Liu, Hongchang, Wang, Xiaoming, Yang, Yonghua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295429/
https://www.ncbi.nlm.nih.gov/pubmed/22412540
http://dx.doi.org/10.1107/S1600536812004369
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author Tian, Runan
Haoriqinbatu,
Liu, Hongchang
Wang, Xiaoming
Yang, Yonghua
author_facet Tian, Runan
Haoriqinbatu,
Liu, Hongchang
Wang, Xiaoming
Yang, Yonghua
author_sort Tian, Runan
collection PubMed
description The title compound, C(19)H(19)NO(10), was obtained from the reaction of α-d-1-bromo-2,3,4-tri-O-acetylxylose with N-hy­droxy­phthalimide in the presence of potassium carbonate. The asymmetric unit contains two independent mol­ecules, in which the O—CH—O—N torsion angles are 73.0 (4) and 65.0 (4)°. The hexa­pyranosyl rings adopt chair conformations and the substituent groups are in equatorial positions. In the crystal, mol­ecules are linked by nonclassical C—H⋯O hydrogen bonds.
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spelling pubmed-32954292012-03-12 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside Tian, Runan Haoriqinbatu, Liu, Hongchang Wang, Xiaoming Yang, Yonghua Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(19)NO(10), was obtained from the reaction of α-d-1-bromo-2,3,4-tri-O-acetylxylose with N-hy­droxy­phthalimide in the presence of potassium carbonate. The asymmetric unit contains two independent mol­ecules, in which the O—CH—O—N torsion angles are 73.0 (4) and 65.0 (4)°. The hexa­pyranosyl rings adopt chair conformations and the substituent groups are in equatorial positions. In the crystal, mol­ecules are linked by nonclassical C—H⋯O hydrogen bonds. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3295429/ /pubmed/22412540 http://dx.doi.org/10.1107/S1600536812004369 Text en © Tian et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tian, Runan
Haoriqinbatu,
Liu, Hongchang
Wang, Xiaoming
Yang, Yonghua
1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside
title 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside
title_full 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside
title_fullStr 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside
title_full_unstemmed 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside
title_short 1,3-Dioxo-2,3-dihydro-1H-isoindol-2-yl 2,3,4-tri-O-acetyl-β-d-xyloside
title_sort 1,3-dioxo-2,3-dihydro-1h-isoindol-2-yl 2,3,4-tri-o-acetyl-β-d-xyloside
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295429/
https://www.ncbi.nlm.nih.gov/pubmed/22412540
http://dx.doi.org/10.1107/S1600536812004369
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AT liuhongchang 13dioxo23dihydro1hisoindol2yl234trioacetylbdxyloside
AT wangxiaoming 13dioxo23dihydro1hisoindol2yl234trioacetylbdxyloside
AT yangyonghua 13dioxo23dihydro1hisoindol2yl234trioacetylbdxyloside

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