Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate

In the asymmetric unit of the title salt, C(3)H(9)S(+)·CH(2)B(11)FI(10)N(−) or (CH(3))(3)S[1-H(2)N-6-F-closo-1-CB(11)I(10)], both ions lie in general positions. The anion is perfectly ordered and so the positions of the C—NH(2) vertex and the fluorine substituent are clearly assigned. The relatively...

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Detalles Bibliográficos
Autores principales: Finze, Maik, Reiss, Guido J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295433/
https://www.ncbi.nlm.nih.gov/pubmed/22412544
http://dx.doi.org/10.1107/S1600536812004424
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author Finze, Maik
Reiss, Guido J.
author_facet Finze, Maik
Reiss, Guido J.
author_sort Finze, Maik
collection PubMed
description In the asymmetric unit of the title salt, C(3)H(9)S(+)·CH(2)B(11)FI(10)N(−) or (CH(3))(3)S[1-H(2)N-6-F-closo-1-CB(11)I(10)], both ions lie in general positions. The anion is perfectly ordered and so the positions of the C—NH(2) vertex and the fluorine substituent are clearly assigned. The relatively short C—N bond length may be inter­preted in terms of a very electron deficient {closo-1-CB(11)} cluster.
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spelling pubmed-32954332012-03-12 Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate Finze, Maik Reiss, Guido J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title salt, C(3)H(9)S(+)·CH(2)B(11)FI(10)N(−) or (CH(3))(3)S[1-H(2)N-6-F-closo-1-CB(11)I(10)], both ions lie in general positions. The anion is perfectly ordered and so the positions of the C—NH(2) vertex and the fluorine substituent are clearly assigned. The relatively short C—N bond length may be inter­preted in terms of a very electron deficient {closo-1-CB(11)} cluster. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3295433/ /pubmed/22412544 http://dx.doi.org/10.1107/S1600536812004424 Text en © Finze and Reiss 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Finze, Maik
Reiss, Guido J.
Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
title Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
title_full Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
title_fullStr Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
title_full_unstemmed Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
title_short Trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
title_sort trimethyl­sulfonium 1-amino-6-fluoro-2,3,4,5,7,8,9,10,11,12-decaiodo-1-carba-closo-dodeca­borate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295433/
https://www.ncbi.nlm.nih.gov/pubmed/22412544
http://dx.doi.org/10.1107/S1600536812004424
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AT reissguidoj trimethylsulfonium1amino6fluoro2345789101112decaiodo1carbaclosododecaborate

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