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rac-4-Carbamoylpiperidinium cis-2-carboxycyclohexane-1-carboxylate
In the title racemic salt, C(6)H(13)N(2)O(+)·C(8)H(11)O(4) (−), formed from the reaction of cis-cyclohexane-1,2-dicarboxylic anhydride with isonipecotamide, the cations are linked into duplex chain substructures through both centrosymmetric cyclic head-to-head ‘amide motif’ hydrogen-bonding assoc...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295451/ https://www.ncbi.nlm.nih.gov/pubmed/22412562 http://dx.doi.org/10.1107/S1600536812004710 |
Sumario: | In the title racemic salt, C(6)H(13)N(2)O(+)·C(8)H(11)O(4) (−), formed from the reaction of cis-cyclohexane-1,2-dicarboxylic anhydride with isonipecotamide, the cations are linked into duplex chain substructures through both centrosymmetric cyclic head-to-head ‘amide motif’ hydrogen-bonding associations [graph set R (2) (2)(8)] and ‘side-by-side’ R (2) (2)(14) associations. The anions are incorporated into the chains through cyclic R (4) (3)(10) interactions involving amide and piperidinium N—H⋯O(carboxyl) hydrogen bonds which, together with inter-anion carboxylic acid O—H⋯O(carboxyl) hydrogen bonds, give a two-dimensional layered structure extending along (011). |
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