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rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate

In the title racemic salt, C(6)H(13)N(2)O(+)·C(8)H(11)O(4) (−), formed from the reaction of cis-cyclo­hexane-1,2-dicarb­oxy­lic anhydride with isonipecotamide, the cations are linked into duplex chain substructures through both centrosymmetric cyclic head-to-head ‘amide motif’ hydrogen-bonding assoc...

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Detalles Bibliográficos
Autores principales: Smith, Graham, Wermuth, Urs D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295451/
https://www.ncbi.nlm.nih.gov/pubmed/22412562
http://dx.doi.org/10.1107/S1600536812004710
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author Smith, Graham
Wermuth, Urs D.
author_facet Smith, Graham
Wermuth, Urs D.
author_sort Smith, Graham
collection PubMed
description In the title racemic salt, C(6)H(13)N(2)O(+)·C(8)H(11)O(4) (−), formed from the reaction of cis-cyclo­hexane-1,2-dicarb­oxy­lic anhydride with isonipecotamide, the cations are linked into duplex chain substructures through both centrosymmetric cyclic head-to-head ‘amide motif’ hydrogen-bonding associations [graph set R (2) (2)(8)] and ‘side-by-side’ R (2) (2)(14) associations. The anions are incorporated into the chains through cyclic R (4) (3)(10) inter­actions involving amide and piperidinium N—H⋯O(carbox­yl) hydrogen bonds which, together with inter-anion carb­oxy­lic acid O—H⋯O(carbox­yl) hydrogen bonds, give a two-dimensional layered structure extending along (011).
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spelling pubmed-32954512012-03-12 rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate Smith, Graham Wermuth, Urs D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title racemic salt, C(6)H(13)N(2)O(+)·C(8)H(11)O(4) (−), formed from the reaction of cis-cyclo­hexane-1,2-dicarb­oxy­lic anhydride with isonipecotamide, the cations are linked into duplex chain substructures through both centrosymmetric cyclic head-to-head ‘amide motif’ hydrogen-bonding associations [graph set R (2) (2)(8)] and ‘side-by-side’ R (2) (2)(14) associations. The anions are incorporated into the chains through cyclic R (4) (3)(10) inter­actions involving amide and piperidinium N—H⋯O(carbox­yl) hydrogen bonds which, together with inter-anion carb­oxy­lic acid O—H⋯O(carbox­yl) hydrogen bonds, give a two-dimensional layered structure extending along (011). International Union of Crystallography 2012-02-10 /pmc/articles/PMC3295451/ /pubmed/22412562 http://dx.doi.org/10.1107/S1600536812004710 Text en © Smith and Wermuth 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Smith, Graham
Wermuth, Urs D.
rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
title rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
title_full rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
title_fullStr rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
title_full_unstemmed rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
title_short rac-4-Carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
title_sort rac-4-carbamoylpiperidinium cis-2-car­boxy­cyclo­hexane-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295451/
https://www.ncbi.nlm.nih.gov/pubmed/22412562
http://dx.doi.org/10.1107/S1600536812004710
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