(6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate

In the mol­ecular structure of the title compound, C(14)H(21)NO(5), the six-membered ring of the indolizine moiety adopts a chair conformation. There are two independent mol­ecules in the asymmetric unit. The oxopyrrolidine ring attached to the indolizine ring system is nearly planar, with mean devi...

Descripción completa

Detalles Bibliográficos
Autores principales: Vrábel, Viktor, Švorc, Ľubomír, Šafář, Peter, Marchalín, Štefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295453/
https://www.ncbi.nlm.nih.gov/pubmed/22412564
http://dx.doi.org/10.1107/S1600536812005144
_version_ 1782225581193035776
author Vrábel, Viktor
Švorc, Ľubomír
Šafář, Peter
Marchalín, Štefan
author_facet Vrábel, Viktor
Švorc, Ľubomír
Šafář, Peter
Marchalín, Štefan
author_sort Vrábel, Viktor
collection PubMed
description In the mol­ecular structure of the title compound, C(14)H(21)NO(5), the six-membered ring of the indolizine moiety adopts a chair conformation. There are two independent mol­ecules in the asymmetric unit. The oxopyrrolidine ring attached to the indolizine ring system is nearly planar, with mean deviations of 0.018 (3) and 0.010 (3) Å for the two mol­ecules. The absolute configuration of the title compound was assigned from the synthesis.
format Online
Article
Text
id pubmed-3295453
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32954532012-03-12 (6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate Vrábel, Viktor Švorc, Ľubomír Šafář, Peter Marchalín, Štefan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecular structure of the title compound, C(14)H(21)NO(5), the six-membered ring of the indolizine moiety adopts a chair conformation. There are two independent mol­ecules in the asymmetric unit. The oxopyrrolidine ring attached to the indolizine ring system is nearly planar, with mean deviations of 0.018 (3) and 0.010 (3) Å for the two mol­ecules. The absolute configuration of the title compound was assigned from the synthesis. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3295453/ /pubmed/22412564 http://dx.doi.org/10.1107/S1600536812005144 Text en © Vrábel et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vrábel, Viktor
Švorc, Ľubomír
Šafář, Peter
Marchalín, Štefan
(6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
title (6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
title_full (6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
title_fullStr (6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
title_full_unstemmed (6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
title_short (6S,7S,8S,8aS)-6-Ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
title_sort (6s,7s,8s,8as)-6-ethyl-3-oxo-1,2,3,5,6,7,8,8a-octa­hydro­indolizine-7,8-diyl diacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295453/
https://www.ncbi.nlm.nih.gov/pubmed/22412564
http://dx.doi.org/10.1107/S1600536812005144
work_keys_str_mv AT vrabelviktor 6s7s8s8as6ethyl3oxo12356788aoctahydroindolizine78diyldiacetate
AT svorclubomir 6s7s8s8as6ethyl3oxo12356788aoctahydroindolizine78diyldiacetate
AT safarpeter 6s7s8s8as6ethyl3oxo12356788aoctahydroindolizine78diyldiacetate
AT marchalinstefan 6s7s8s8as6ethyl3oxo12356788aoctahydroindolizine78diyldiacetate

Ejemplares similares