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2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one
In the title aza-flavanone, C(18)H(19)NO(4), an intramolecular cyclization product of chalcone, the central heterocyclic ring is in an envelope conformation and the dihedral angle between the benzene rings is 51.03 (10)°. The methoxy groups at the ortho and para positions are slightly twisted from...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295454/ https://www.ncbi.nlm.nih.gov/pubmed/22412565 http://dx.doi.org/10.1107/S1600536812002917 |
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author | Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chantrapromma, Kan Fun, Hoong-Kun |
author_facet | Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chantrapromma, Kan Fun, Hoong-Kun |
author_sort | Chantrapromma, Suchada |
collection | PubMed |
description | In the title aza-flavanone, C(18)H(19)NO(4), an intramolecular cyclization product of chalcone, the central heterocyclic ring is in an envelope conformation and the dihedral angle between the benzene rings is 51.03 (10)°. The methoxy groups at the ortho and para positions are slightly twisted from the benzene ring to which they are bound [C—O—C—C = 21.9 (3) and −171.93 (18)°, respectively], whereas the methoxy group at the meta position is almost coplanar [C—O—C—C = 3.5 (3)°]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O interactions into chains along the [001] direction. Weak C—H⋯π interactions also occur. |
format | Online Article Text |
id | pubmed-3295454 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32954542012-03-12 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chantrapromma, Kan Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title aza-flavanone, C(18)H(19)NO(4), an intramolecular cyclization product of chalcone, the central heterocyclic ring is in an envelope conformation and the dihedral angle between the benzene rings is 51.03 (10)°. The methoxy groups at the ortho and para positions are slightly twisted from the benzene ring to which they are bound [C—O—C—C = 21.9 (3) and −171.93 (18)°, respectively], whereas the methoxy group at the meta position is almost coplanar [C—O—C—C = 3.5 (3)°]. In the crystal, molecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O interactions into chains along the [001] direction. Weak C—H⋯π interactions also occur. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3295454/ /pubmed/22412565 http://dx.doi.org/10.1107/S1600536812002917 Text en © Chantrapromma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chantrapromma, Kan Fun, Hoong-Kun 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one |
title | 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one |
title_full | 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one |
title_fullStr | 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one |
title_full_unstemmed | 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one |
title_short | 2-(2,4,5-Trimethoxyphenyl)-2,3-dihydroquinolin-4(1H)-one |
title_sort | 2-(2,4,5-trimethoxyphenyl)-2,3-dihydroquinolin-4(1h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295454/ https://www.ncbi.nlm.nih.gov/pubmed/22412565 http://dx.doi.org/10.1107/S1600536812002917 |
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