Cargando…

2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one

In the title aza-flavanone, C(18)H(19)NO(4), an intra­molecular cyclization product of chalcone, the central heterocyclic ring is in an envelope conformation and the dihedral angle between the benzene rings is 51.03 (10)°. The meth­oxy groups at the ortho and para positions are slightly twisted from...

Descripción completa

Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Ruanwas, Pumsak, Boonnak, Nawong, Chantrapromma, Kan, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295454/
https://www.ncbi.nlm.nih.gov/pubmed/22412565
http://dx.doi.org/10.1107/S1600536812002917
_version_ 1782225581421625344
author Chantrapromma, Suchada
Ruanwas, Pumsak
Boonnak, Nawong
Chantrapromma, Kan
Fun, Hoong-Kun
author_facet Chantrapromma, Suchada
Ruanwas, Pumsak
Boonnak, Nawong
Chantrapromma, Kan
Fun, Hoong-Kun
author_sort Chantrapromma, Suchada
collection PubMed
description In the title aza-flavanone, C(18)H(19)NO(4), an intra­molecular cyclization product of chalcone, the central heterocyclic ring is in an envelope conformation and the dihedral angle between the benzene rings is 51.03 (10)°. The meth­oxy groups at the ortho and para positions are slightly twisted from the benzene ring to which they are bound [C—O—C—C = 21.9 (3) and −171.93 (18)°, respectively], whereas the meth­oxy group at the meta position is almost coplanar [C—O—C—C = 3.5 (3)°]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions into chains along the [001] direction. Weak C—H⋯π inter­actions also occur.
format Online
Article
Text
id pubmed-3295454
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32954542012-03-12 2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one Chantrapromma, Suchada Ruanwas, Pumsak Boonnak, Nawong Chantrapromma, Kan Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title aza-flavanone, C(18)H(19)NO(4), an intra­molecular cyclization product of chalcone, the central heterocyclic ring is in an envelope conformation and the dihedral angle between the benzene rings is 51.03 (10)°. The meth­oxy groups at the ortho and para positions are slightly twisted from the benzene ring to which they are bound [C—O—C—C = 21.9 (3) and −171.93 (18)°, respectively], whereas the meth­oxy group at the meta position is almost coplanar [C—O—C—C = 3.5 (3)°]. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds and weak C—H⋯O inter­actions into chains along the [001] direction. Weak C—H⋯π inter­actions also occur. International Union of Crystallography 2012-02-10 /pmc/articles/PMC3295454/ /pubmed/22412565 http://dx.doi.org/10.1107/S1600536812002917 Text en © Chantrapromma et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chantrapromma, Suchada
Ruanwas, Pumsak
Boonnak, Nawong
Chantrapromma, Kan
Fun, Hoong-Kun
2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one
title 2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one
title_full 2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one
title_fullStr 2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one
title_full_unstemmed 2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one
title_short 2-(2,4,5-Trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1H)-one
title_sort 2-(2,4,5-trimeth­oxy­phen­yl)-2,3-dihydro­quinolin-4(1h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295454/
https://www.ncbi.nlm.nih.gov/pubmed/22412565
http://dx.doi.org/10.1107/S1600536812002917
work_keys_str_mv AT chantraprommasuchada 2245trimethoxyphenyl23dihydroquinolin41hone
AT ruanwaspumsak 2245trimethoxyphenyl23dihydroquinolin41hone
AT boonnaknawong 2245trimethoxyphenyl23dihydroquinolin41hone
AT chantraprommakan 2245trimethoxyphenyl23dihydroquinolin41hone
AT funhoongkun 2245trimethoxyphenyl23dihydroquinolin41hone