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Secohellebrigeninamide
The title compound, C(26)H(37)NO(5), was the reaction product of hellebrigenin with N,N-dimethylformamide. It consists of three cyclohexane rings (A, B and C), one five-membered ring (D) and one dihydropyran ring (E). The stereochemistry of the ring junctions is is A/B cis, B/C trans, C/D cis and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295466/ https://www.ncbi.nlm.nih.gov/pubmed/22412577 http://dx.doi.org/10.1107/S160053681200520X |
Sumario: | The title compound, C(26)H(37)NO(5), was the reaction product of hellebrigenin with N,N-dimethylformamide. It consists of three cyclohexane rings (A, B and C), one five-membered ring (D) and one dihydropyran ring (E). The stereochemistry of the ring junctions is is A/B cis, B/C trans, C/D cis and C/E trans. The cyclohexane rings A, B and C have chair conformations. Both the five-membered ring D and the dihydropyran ring adopt an envelope conformation. Two orientations are found for the aldehyde group with occupancies of 0.608 (10) and 0.392 (10). In the crystal, short O—H⋯O hydrogen bonds and short C—H⋯O contacts involving the hydroxy group, terminal methyl group and carbonyl group link the molecules into a three-dimensional network. |
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