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Secohellebrigeninamide

The title compound, C(26)H(37)NO(5), was the reaction product of hellebrigenin with N,N-dimethyl­formamide. It consists of three cyclo­hexane rings (A, B and C), one five-membered ring (D) and one dihydro­pyran ring (E). The stereochemistry of the ring junctions is is A/B cis, B/C trans, C/D cis and...

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Detalles Bibliográficos
Autores principales: Yuan, Xiao-Feng, Tian, Hai-Yan, Li, Jin-Hang, Yu, Tong, Jiang, Ren-Wang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3295466/
https://www.ncbi.nlm.nih.gov/pubmed/22412577
http://dx.doi.org/10.1107/S160053681200520X
Descripción
Sumario:The title compound, C(26)H(37)NO(5), was the reaction product of hellebrigenin with N,N-dimethyl­formamide. It consists of three cyclo­hexane rings (A, B and C), one five-membered ring (D) and one dihydro­pyran ring (E). The stereochemistry of the ring junctions is is A/B cis, B/C trans, C/D cis and C/E trans. The cyclo­hexane rings A, B and C have chair conformations. Both the five-membered ring D and the dihydro­pyran ring adopt an envelope conformation. Two orientations are found for the aldehyde group with occupancies of 0.608 (10) and 0.392 (10). In the crystal, short O—H⋯O hydrogen bonds and short C—H⋯O contacts involving the hy­droxy group, terminal methyl group and carbonyl group link the mol­ecules into a three-dimensional network.